9-{4-[(E)-2-(4,6-Dimethyl-1,3,5-triazin-2-yl)ethen­yl]phen­yl}-9H-carbazole

In the crystal structure of the title compound, C(25)H(20)N(4), the triazinyl ring is nearly coplanar with the planar (r.m.s. deviation = 0.028 Å) phenyl­ethenyl unit, the twist being only 5.8 (2)°; however, the planar carbazolyl unit (r.m.s. deviation = 0.008 Å) is twisted by 47.8 (1)° with respect...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Chang-Lin, Xue, Gang, Cui, Yue-Zhi, Li, Tian-Duo, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970030/
https://www.ncbi.nlm.nih.gov/pubmed/21577511
http://dx.doi.org/10.1107/S1600536809030359
_version_ 1782190326300016640
author Liu, Chang-Lin
Xue, Gang
Cui, Yue-Zhi
Li, Tian-Duo
Ng, Seik Weng
author_facet Liu, Chang-Lin
Xue, Gang
Cui, Yue-Zhi
Li, Tian-Duo
Ng, Seik Weng
author_sort Liu, Chang-Lin
collection PubMed
description In the crystal structure of the title compound, C(25)H(20)N(4), the triazinyl ring is nearly coplanar with the planar (r.m.s. deviation = 0.028 Å) phenyl­ethenyl unit, the twist being only 5.8 (2)°; however, the planar carbazolyl unit (r.m.s. deviation = 0.008 Å) is twisted by 47.8 (1)° with respect to the phenyl­ethenyl unit. The nonplanar nature of the mol­ecule explains the phenomenon of light emission at short wavelengths in the solid state but at long wavelengths in solution.
format Text
id pubmed-2970030
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29700302010-12-30 9-{4-[(E)-2-(4,6-Dimethyl-1,3,5-triazin-2-yl)ethen­yl]phen­yl}-9H-carbazole Liu, Chang-Lin Xue, Gang Cui, Yue-Zhi Li, Tian-Duo Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(25)H(20)N(4), the triazinyl ring is nearly coplanar with the planar (r.m.s. deviation = 0.028 Å) phenyl­ethenyl unit, the twist being only 5.8 (2)°; however, the planar carbazolyl unit (r.m.s. deviation = 0.008 Å) is twisted by 47.8 (1)° with respect to the phenyl­ethenyl unit. The nonplanar nature of the mol­ecule explains the phenomenon of light emission at short wavelengths in the solid state but at long wavelengths in solution. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970030/ /pubmed/21577511 http://dx.doi.org/10.1107/S1600536809030359 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Chang-Lin
Xue, Gang
Cui, Yue-Zhi
Li, Tian-Duo
Ng, Seik Weng
9-{4-[(E)-2-(4,6-Dimethyl-1,3,5-triazin-2-yl)ethen­yl]phen­yl}-9H-carbazole
title 9-{4-[(E)-2-(4,6-Dimethyl-1,3,5-triazin-2-yl)ethen­yl]phen­yl}-9H-carbazole
title_full 9-{4-[(E)-2-(4,6-Dimethyl-1,3,5-triazin-2-yl)ethen­yl]phen­yl}-9H-carbazole
title_fullStr 9-{4-[(E)-2-(4,6-Dimethyl-1,3,5-triazin-2-yl)ethen­yl]phen­yl}-9H-carbazole
title_full_unstemmed 9-{4-[(E)-2-(4,6-Dimethyl-1,3,5-triazin-2-yl)ethen­yl]phen­yl}-9H-carbazole
title_short 9-{4-[(E)-2-(4,6-Dimethyl-1,3,5-triazin-2-yl)ethen­yl]phen­yl}-9H-carbazole
title_sort 9-{4-[(e)-2-(4,6-dimethyl-1,3,5-triazin-2-yl)ethen­yl]phen­yl}-9h-carbazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970030/
https://www.ncbi.nlm.nih.gov/pubmed/21577511
http://dx.doi.org/10.1107/S1600536809030359
work_keys_str_mv AT liuchanglin 94e246dimethyl135triazin2ylethenylphenyl9hcarbazole
AT xuegang 94e246dimethyl135triazin2ylethenylphenyl9hcarbazole
AT cuiyuezhi 94e246dimethyl135triazin2ylethenylphenyl9hcarbazole
AT litianduo 94e246dimethyl135triazin2ylethenylphenyl9hcarbazole
AT ngseikweng 94e246dimethyl135triazin2ylethenylphenyl9hcarbazole

Ejemplares similares