4,11-Diaza-1,8-diazo­niacyclo­tetra­decane dichloride hemihydrate

In the title compound, C(10)H(26)N(4) (2+)·2Cl(−)·0.5H(2)O, the cyclam (1,4,8,11-tetra­azacyclo­tetra­decane) dication adopts an endodentate conformation which my be inflenced by intra­molecular N—H⋯N hydrogen bonding. In the crystal structure, the components are linked by N—H⋯Cl and O—H⋯Cl hydrogen...

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Detalles Bibliográficos
Autores principales: Kim, Nam-Ho, Hwang, In-Chul, Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970031/
https://www.ncbi.nlm.nih.gov/pubmed/21577540
http://dx.doi.org/10.1107/S1600536809031110
Descripción
Sumario:In the title compound, C(10)H(26)N(4) (2+)·2Cl(−)·0.5H(2)O, the cyclam (1,4,8,11-tetra­azacyclo­tetra­decane) dication adopts an endodentate conformation which my be inflenced by intra­molecular N—H⋯N hydrogen bonding. In the crystal structure, the components are linked by N—H⋯Cl and O—H⋯Cl hydrogen bonds into chains along [100]. The water molecule is disordered over two sites in a 50:50 ratio.

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