Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate

The crystal structure of the title compound, [PtBr(C(15)H(11)N(3))][AuBr(2)]·(CH(3))(2)SO, exhibits infinite chains of {PtAuPt}(∞) metallophilic inter­actions along the b axis. Two cations and one anion stack in a trimer with a unique Pt⋯Au distance of 3.3361 (5) Å and Pt⋯Pt contacts of 3.4335 (6) Å...

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Autores principales: Kahn, Michael I., Golen, James A., Rheingold, Arnold L., Doerrer, Linda H.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970032/
https://www.ncbi.nlm.nih.gov/pubmed/21577472
http://dx.doi.org/10.1107/S1600536809033248
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author Kahn, Michael I.
Golen, James A.
Rheingold, Arnold L.
Doerrer, Linda H.
author_facet Kahn, Michael I.
Golen, James A.
Rheingold, Arnold L.
Doerrer, Linda H.
author_sort Kahn, Michael I.
collection PubMed
description The crystal structure of the title compound, [PtBr(C(15)H(11)N(3))][AuBr(2)]·(CH(3))(2)SO, exhibits infinite chains of {PtAuPt}(∞) metallophilic inter­actions along the b axis. Two cations and one anion stack in a trimer with a unique Pt⋯Au distance of 3.3361 (5) Å and Pt⋯Pt contacts of 3.4335 (6) Å. The remaining [AuBr(2)](−) anion forms no close contacts.
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spelling pubmed-29700322010-12-30 Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate Kahn, Michael I. Golen, James A. Rheingold, Arnold L. Doerrer, Linda H. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [PtBr(C(15)H(11)N(3))][AuBr(2)]·(CH(3))(2)SO, exhibits infinite chains of {PtAuPt}(∞) metallophilic inter­actions along the b axis. Two cations and one anion stack in a trimer with a unique Pt⋯Au distance of 3.3361 (5) Å and Pt⋯Pt contacts of 3.4335 (6) Å. The remaining [AuBr(2)](−) anion forms no close contacts. International Union of Crystallography 2009-08-26 /pmc/articles/PMC2970032/ /pubmed/21577472 http://dx.doi.org/10.1107/S1600536809033248 Text en © Kahn et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kahn, Michael I.
Golen, James A.
Rheingold, Arnold L.
Doerrer, Linda H.
Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate
title Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate
title_full Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate
title_fullStr Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate
title_full_unstemmed Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate
title_short Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate
title_sort bromido(2,2′:6′,2′′-terpyridine)platinum(ii) dibromidoaurate(i) dimethyl sulfoxide solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970032/
https://www.ncbi.nlm.nih.gov/pubmed/21577472
http://dx.doi.org/10.1107/S1600536809033248
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AT rheingoldarnoldl bromido2262terpyridineplatinumiidibromidoaurateidimethylsulfoxidesolvate
AT doerrerlindah bromido2262terpyridineplatinumiidibromidoaurateidimethylsulfoxidesolvate

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