Difluoridodioxido(1,10-phenanthroline)molybdenum(VI)

The title compound, [MoF(2)O(2)(C(12)H(8)N(2))], has non-crystallographic mirror symmetry. The Mo(VI) atom shows a distorted octa­hedral environment, with the phenanthroline N atoms and the two oxide groups forming the equatorial plane and the F atoms occupying the apical positions. Weak C—H⋯O and C...

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Detalles Bibliográficos
Autores principales: Wang, Wenju, Zhang, Youdi, Jin, Xiangjun, Du, Xiguang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970040/
https://www.ncbi.nlm.nih.gov/pubmed/21577445
http://dx.doi.org/10.1107/S1600536809031626
Descripción
Sumario:The title compound, [MoF(2)O(2)(C(12)H(8)N(2))], has non-crystallographic mirror symmetry. The Mo(VI) atom shows a distorted octa­hedral environment, with the phenanthroline N atoms and the two oxide groups forming the equatorial plane and the F atoms occupying the apical positions. Weak C—H⋯O and C—H⋯F hydrogen-bonding contacts and π–π inter­actions [centroid–centroid distance = 3.662 (1) Å] connect the complex mol­ecules into a three-dimensional supra­molecular framework.

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