Difluoridodioxido(1,10-phenanthroline)molybdenum(VI)

The title compound, [MoF(2)O(2)(C(12)H(8)N(2))], has non-crystallographic mirror symmetry. The Mo(VI) atom shows a distorted octa­hedral environment, with the phenanthroline N atoms and the two oxide groups forming the equatorial plane and the F atoms occupying the apical positions. Weak C—H⋯O and C...

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Detalles Bibliográficos
Autores principales: Wang, Wenju, Zhang, Youdi, Jin, Xiangjun, Du, Xiguang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970040/
https://www.ncbi.nlm.nih.gov/pubmed/21577445
http://dx.doi.org/10.1107/S1600536809031626
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author Wang, Wenju
Zhang, Youdi
Jin, Xiangjun
Du, Xiguang
author_facet Wang, Wenju
Zhang, Youdi
Jin, Xiangjun
Du, Xiguang
author_sort Wang, Wenju
collection PubMed
description The title compound, [MoF(2)O(2)(C(12)H(8)N(2))], has non-crystallographic mirror symmetry. The Mo(VI) atom shows a distorted octa­hedral environment, with the phenanthroline N atoms and the two oxide groups forming the equatorial plane and the F atoms occupying the apical positions. Weak C—H⋯O and C—H⋯F hydrogen-bonding contacts and π–π inter­actions [centroid–centroid distance = 3.662 (1) Å] connect the complex mol­ecules into a three-dimensional supra­molecular framework.
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spelling pubmed-29700402010-12-30 Difluoridodioxido(1,10-phenanthroline)molybdenum(VI) Wang, Wenju Zhang, Youdi Jin, Xiangjun Du, Xiguang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [MoF(2)O(2)(C(12)H(8)N(2))], has non-crystallographic mirror symmetry. The Mo(VI) atom shows a distorted octa­hedral environment, with the phenanthroline N atoms and the two oxide groups forming the equatorial plane and the F atoms occupying the apical positions. Weak C—H⋯O and C—H⋯F hydrogen-bonding contacts and π–π inter­actions [centroid–centroid distance = 3.662 (1) Å] connect the complex mol­ecules into a three-dimensional supra­molecular framework. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970040/ /pubmed/21577445 http://dx.doi.org/10.1107/S1600536809031626 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Wenju
Zhang, Youdi
Jin, Xiangjun
Du, Xiguang
Difluoridodioxido(1,10-phenanthroline)molybdenum(VI)
title Difluoridodioxido(1,10-phenanthroline)molybdenum(VI)
title_full Difluoridodioxido(1,10-phenanthroline)molybdenum(VI)
title_fullStr Difluoridodioxido(1,10-phenanthroline)molybdenum(VI)
title_full_unstemmed Difluoridodioxido(1,10-phenanthroline)molybdenum(VI)
title_short Difluoridodioxido(1,10-phenanthroline)molybdenum(VI)
title_sort difluoridodioxido(1,10-phenanthroline)molybdenum(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970040/
https://www.ncbi.nlm.nih.gov/pubmed/21577445
http://dx.doi.org/10.1107/S1600536809031626
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AT jinxiangjun difluoridodioxido110phenanthrolinemolybdenumvi
AT duxiguang difluoridodioxido110phenanthrolinemolybdenumvi

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