1-Chloro­acetyl-2,6-bis­(2-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one

The piperidone ring in the title compound, C(23)H(26)ClNO(4), adopts a boat conformation with its two out-of-plane C atoms deviating by 0.597 (2) and 0.630 (2) Å from the least-squares plane of the rest of atoms in the ring. The two aromatic rings are roughly perpendicular to each other, making a di...

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Detalles Bibliográficos
Autores principales: Aridoss, G., Gayathri, D., Velmurugan, D., Kim, M. S., Jeong, Yeon Tae
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970045/
https://www.ncbi.nlm.nih.gov/pubmed/21577671
http://dx.doi.org/10.1107/S1600536809033674
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author Aridoss, G.
Gayathri, D.
Velmurugan, D.
Kim, M. S.
Jeong, Yeon Tae
author_facet Aridoss, G.
Gayathri, D.
Velmurugan, D.
Kim, M. S.
Jeong, Yeon Tae
author_sort Aridoss, G.
collection PubMed
description The piperidone ring in the title compound, C(23)H(26)ClNO(4), adopts a boat conformation with its two out-of-plane C atoms deviating by 0.597 (2) and 0.630 (2) Å from the least-squares plane of the rest of atoms in the ring. The two aromatic rings are roughly perpendicular to each other, making a dihedral angle of 75.1 (1)°, and a C—H⋯π intra­molecular inter­action is observed. The crystal packing is stabilized by a C—H⋯O inter­molecular inter­action, generating a chain with a C(9) motif along the a axis.
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spelling pubmed-29700452010-12-30 1-Chloro­acetyl-2,6-bis­(2-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one Aridoss, G. Gayathri, D. Velmurugan, D. Kim, M. S. Jeong, Yeon Tae Acta Crystallogr Sect E Struct Rep Online Organic Papers The piperidone ring in the title compound, C(23)H(26)ClNO(4), adopts a boat conformation with its two out-of-plane C atoms deviating by 0.597 (2) and 0.630 (2) Å from the least-squares plane of the rest of atoms in the ring. The two aromatic rings are roughly perpendicular to each other, making a dihedral angle of 75.1 (1)°, and a C—H⋯π intra­molecular inter­action is observed. The crystal packing is stabilized by a C—H⋯O inter­molecular inter­action, generating a chain with a C(9) motif along the a axis. International Union of Crystallography 2009-08-29 /pmc/articles/PMC2970045/ /pubmed/21577671 http://dx.doi.org/10.1107/S1600536809033674 Text en © Aridoss et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Aridoss, G.
Gayathri, D.
Velmurugan, D.
Kim, M. S.
Jeong, Yeon Tae
1-Chloro­acetyl-2,6-bis­(2-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title 1-Chloro­acetyl-2,6-bis­(2-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title_full 1-Chloro­acetyl-2,6-bis­(2-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title_fullStr 1-Chloro­acetyl-2,6-bis­(2-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title_full_unstemmed 1-Chloro­acetyl-2,6-bis­(2-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title_short 1-Chloro­acetyl-2,6-bis­(2-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title_sort 1-chloro­acetyl-2,6-bis­(2-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970045/
https://www.ncbi.nlm.nih.gov/pubmed/21577671
http://dx.doi.org/10.1107/S1600536809033674
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AT gayathrid 1chloroacetyl26bis2methoxyphenyl35dimethylpiperidin4one
AT velmurugand 1chloroacetyl26bis2methoxyphenyl35dimethylpiperidin4one
AT kimms 1chloroacetyl26bis2methoxyphenyl35dimethylpiperidin4one
AT jeongyeontae 1chloroacetyl26bis2methoxyphenyl35dimethylpiperidin4one

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