Cargando…

Dichlorido{μ(3)-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}octa­methyldi-μ(3)-oxido-tetra­tin(IV)

In the title tetra­nuclear tin(IV) complex, [Sn(4)(CH(3))(8)(C(20)H(22)N(2)O(4))Cl(2)O(2)], there are three completely different tin-atom coordinations. One metal atom (site symmetry 2) adopts a distorted penta­gonal-bipyramidal SnC(2)N(2)O(3) coordination arising from the N,N′,O,O′-tetra­dentate de...

Descripción completa

Detalles Bibliográficos
Autores principales: Lee, See Mun, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970047/
https://www.ncbi.nlm.nih.gov/pubmed/21577451
http://dx.doi.org/10.1107/S1600536809032255
_version_ 1782190330895925248
author Lee, See Mun
Lo, Kong Mun
Ng, Seik Weng
author_facet Lee, See Mun
Lo, Kong Mun
Ng, Seik Weng
author_sort Lee, See Mun
collection PubMed
description In the title tetra­nuclear tin(IV) complex, [Sn(4)(CH(3))(8)(C(20)H(22)N(2)O(4))Cl(2)O(2)], there are three completely different tin-atom coordinations. One metal atom (site symmetry 2) adopts a distorted penta­gonal-bipyramidal SnC(2)N(2)O(3) coordination arising from the N,N′,O,O′-tetra­dentate deprotonated Schiff base, two methyl groups in the axial sites and a μ(3)-O atom that also bonds to two further Sn atoms. Two symmetry-equivalent Sn atoms adopt very distorted SnC(2)O(4) arrangements that could be described as penta­gonal-bipyramidal with one equatorial vertex missing and the C atoms in the axial site. The final Sn atom (site symmetry 2) adopts an SnC(2)Cl(2)O trigonal-bipyramidal arrangement, with Cl atoms in the axial sites. As well as the two Sn atoms, one O atom lies on a twofold rotation rotation axis, and another is disordered about the axis. The terminal eth­oxy group is disordered over two sets of sites with equal occupancy.
format Text
id pubmed-2970047
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29700472010-12-30 Dichlorido{μ(3)-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}octa­methyldi-μ(3)-oxido-tetra­tin(IV) Lee, See Mun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title tetra­nuclear tin(IV) complex, [Sn(4)(CH(3))(8)(C(20)H(22)N(2)O(4))Cl(2)O(2)], there are three completely different tin-atom coordinations. One metal atom (site symmetry 2) adopts a distorted penta­gonal-bipyramidal SnC(2)N(2)O(3) coordination arising from the N,N′,O,O′-tetra­dentate deprotonated Schiff base, two methyl groups in the axial sites and a μ(3)-O atom that also bonds to two further Sn atoms. Two symmetry-equivalent Sn atoms adopt very distorted SnC(2)O(4) arrangements that could be described as penta­gonal-bipyramidal with one equatorial vertex missing and the C atoms in the axial site. The final Sn atom (site symmetry 2) adopts an SnC(2)Cl(2)O trigonal-bipyramidal arrangement, with Cl atoms in the axial sites. As well as the two Sn atoms, one O atom lies on a twofold rotation rotation axis, and another is disordered about the axis. The terminal eth­oxy group is disordered over two sets of sites with equal occupancy. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970047/ /pubmed/21577451 http://dx.doi.org/10.1107/S1600536809032255 Text en © Lee et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, See Mun
Lo, Kong Mun
Ng, Seik Weng
Dichlorido{μ(3)-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}octa­methyldi-μ(3)-oxido-tetra­tin(IV)
title Dichlorido{μ(3)-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}octa­methyldi-μ(3)-oxido-tetra­tin(IV)
title_full Dichlorido{μ(3)-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}octa­methyldi-μ(3)-oxido-tetra­tin(IV)
title_fullStr Dichlorido{μ(3)-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}octa­methyldi-μ(3)-oxido-tetra­tin(IV)
title_full_unstemmed Dichlorido{μ(3)-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}octa­methyldi-μ(3)-oxido-tetra­tin(IV)
title_short Dichlorido{μ(3)-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}octa­methyldi-μ(3)-oxido-tetra­tin(IV)
title_sort dichlorido{μ(3)-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}octa­methyldi-μ(3)-oxido-tetra­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970047/
https://www.ncbi.nlm.nih.gov/pubmed/21577451
http://dx.doi.org/10.1107/S1600536809032255
work_keys_str_mv AT leeseemun dichloridom366diethoxy22ethane12diylbisnitrilomethylidynediphenolatooctamethyldim3oxidotetratiniv
AT lokongmun dichloridom366diethoxy22ethane12diylbisnitrilomethylidynediphenolatooctamethyldim3oxidotetratiniv
AT ngseikweng dichloridom366diethoxy22ethane12diylbisnitrilomethylidynediphenolatooctamethyldim3oxidotetratiniv