Cargando…
Dichlorido{μ(3)-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}octamethyldi-μ(3)-oxido-tetratin(IV)
In the title tetranuclear tin(IV) complex, [Sn(4)(CH(3))(8)(C(20)H(22)N(2)O(4))Cl(2)O(2)], there are three completely different tin-atom coordinations. One metal atom (site symmetry 2) adopts a distorted pentagonal-bipyramidal SnC(2)N(2)O(3) coordination arising from the N,N′,O,O′-tetradentate de...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970047/ https://www.ncbi.nlm.nih.gov/pubmed/21577451 http://dx.doi.org/10.1107/S1600536809032255 |
_version_ | 1782190330895925248 |
---|---|
author | Lee, See Mun Lo, Kong Mun Ng, Seik Weng |
author_facet | Lee, See Mun Lo, Kong Mun Ng, Seik Weng |
author_sort | Lee, See Mun |
collection | PubMed |
description | In the title tetranuclear tin(IV) complex, [Sn(4)(CH(3))(8)(C(20)H(22)N(2)O(4))Cl(2)O(2)], there are three completely different tin-atom coordinations. One metal atom (site symmetry 2) adopts a distorted pentagonal-bipyramidal SnC(2)N(2)O(3) coordination arising from the N,N′,O,O′-tetradentate deprotonated Schiff base, two methyl groups in the axial sites and a μ(3)-O atom that also bonds to two further Sn atoms. Two symmetry-equivalent Sn atoms adopt very distorted SnC(2)O(4) arrangements that could be described as pentagonal-bipyramidal with one equatorial vertex missing and the C atoms in the axial site. The final Sn atom (site symmetry 2) adopts an SnC(2)Cl(2)O trigonal-bipyramidal arrangement, with Cl atoms in the axial sites. As well as the two Sn atoms, one O atom lies on a twofold rotation rotation axis, and another is disordered about the axis. The terminal ethoxy group is disordered over two sets of sites with equal occupancy. |
format | Text |
id | pubmed-2970047 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29700472010-12-30 Dichlorido{μ(3)-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}octamethyldi-μ(3)-oxido-tetratin(IV) Lee, See Mun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title tetranuclear tin(IV) complex, [Sn(4)(CH(3))(8)(C(20)H(22)N(2)O(4))Cl(2)O(2)], there are three completely different tin-atom coordinations. One metal atom (site symmetry 2) adopts a distorted pentagonal-bipyramidal SnC(2)N(2)O(3) coordination arising from the N,N′,O,O′-tetradentate deprotonated Schiff base, two methyl groups in the axial sites and a μ(3)-O atom that also bonds to two further Sn atoms. Two symmetry-equivalent Sn atoms adopt very distorted SnC(2)O(4) arrangements that could be described as pentagonal-bipyramidal with one equatorial vertex missing and the C atoms in the axial site. The final Sn atom (site symmetry 2) adopts an SnC(2)Cl(2)O trigonal-bipyramidal arrangement, with Cl atoms in the axial sites. As well as the two Sn atoms, one O atom lies on a twofold rotation rotation axis, and another is disordered about the axis. The terminal ethoxy group is disordered over two sets of sites with equal occupancy. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970047/ /pubmed/21577451 http://dx.doi.org/10.1107/S1600536809032255 Text en © Lee et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lee, See Mun Lo, Kong Mun Ng, Seik Weng Dichlorido{μ(3)-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}octamethyldi-μ(3)-oxido-tetratin(IV) |
title | Dichlorido{μ(3)-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}octamethyldi-μ(3)-oxido-tetratin(IV) |
title_full | Dichlorido{μ(3)-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}octamethyldi-μ(3)-oxido-tetratin(IV) |
title_fullStr | Dichlorido{μ(3)-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}octamethyldi-μ(3)-oxido-tetratin(IV) |
title_full_unstemmed | Dichlorido{μ(3)-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}octamethyldi-μ(3)-oxido-tetratin(IV) |
title_short | Dichlorido{μ(3)-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}octamethyldi-μ(3)-oxido-tetratin(IV) |
title_sort | dichlorido{μ(3)-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}octamethyldi-μ(3)-oxido-tetratin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970047/ https://www.ncbi.nlm.nih.gov/pubmed/21577451 http://dx.doi.org/10.1107/S1600536809032255 |
work_keys_str_mv | AT leeseemun dichloridom366diethoxy22ethane12diylbisnitrilomethylidynediphenolatooctamethyldim3oxidotetratiniv AT lokongmun dichloridom366diethoxy22ethane12diylbisnitrilomethylidynediphenolatooctamethyldim3oxidotetratiniv AT ngseikweng dichloridom366diethoxy22ethane12diylbisnitrilomethylidynediphenolatooctamethyldim3oxidotetratiniv |