Tetra­aqua­bis{2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetato}manganese(II) dihydrate

In the title compound, [Mn(C(11)H(8)N(3)O(2)S)(2)(H(2)O)(4)]·2H(2)O, the Mn(II) ion lies on an inversion centre and is coordinated by four water mol­ecules in equatorial positions and two N atoms from two 2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetate ligands in the axial positions. The water mol­...

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Detalles Bibliográficos
Autores principales: Zhu, Hai-Bin, Xu, Gang, Sun, Yan-Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970048/
https://www.ncbi.nlm.nih.gov/pubmed/21577466
http://dx.doi.org/10.1107/S1600536809033078
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author Zhu, Hai-Bin
Xu, Gang
Sun, Yan-Yan
author_facet Zhu, Hai-Bin
Xu, Gang
Sun, Yan-Yan
author_sort Zhu, Hai-Bin
collection PubMed
description In the title compound, [Mn(C(11)H(8)N(3)O(2)S)(2)(H(2)O)(4)]·2H(2)O, the Mn(II) ion lies on an inversion centre and is coordinated by four water mol­ecules in equatorial positions and two N atoms from two 2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetate ligands in the axial positions. The water mol­ecules, including the uncoordinated water mol­ecules, and the acetate O atoms are involved in O—H⋯O and O—H⋯N hydrogen-bonding inter­actions, which link the components into layers parallel to the a (b + c) plane.
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spelling pubmed-29700482010-12-30 Tetra­aqua­bis{2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetato}manganese(II) dihydrate Zhu, Hai-Bin Xu, Gang Sun, Yan-Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(11)H(8)N(3)O(2)S)(2)(H(2)O)(4)]·2H(2)O, the Mn(II) ion lies on an inversion centre and is coordinated by four water mol­ecules in equatorial positions and two N atoms from two 2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetate ligands in the axial positions. The water mol­ecules, including the uncoordinated water mol­ecules, and the acetate O atoms are involved in O—H⋯O and O—H⋯N hydrogen-bonding inter­actions, which link the components into layers parallel to the a (b + c) plane. International Union of Crystallography 2009-08-22 /pmc/articles/PMC2970048/ /pubmed/21577466 http://dx.doi.org/10.1107/S1600536809033078 Text en © Zhu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Hai-Bin
Xu, Gang
Sun, Yan-Yan
Tetra­aqua­bis{2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetato}manganese(II) dihydrate
title Tetra­aqua­bis{2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetato}manganese(II) dihydrate
title_full Tetra­aqua­bis{2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetato}manganese(II) dihydrate
title_fullStr Tetra­aqua­bis{2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetato}manganese(II) dihydrate
title_full_unstemmed Tetra­aqua­bis{2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetato}manganese(II) dihydrate
title_short Tetra­aqua­bis{2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetato}manganese(II) dihydrate
title_sort tetra­aqua­bis{2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetato}manganese(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970048/
https://www.ncbi.nlm.nih.gov/pubmed/21577466
http://dx.doi.org/10.1107/S1600536809033078
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AT xugang tetraaquabis243pyridylpyrimidin2ylsulfanylacetatomanganeseiidihydrate
AT sunyanyan tetraaquabis243pyridylpyrimidin2ylsulfanylacetatomanganeseiidihydrate

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