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N-Acetonylsaccharin

In the title compound [systematic name: 2-(2-oxoprop­yl)-1,2-benzothia­zol-3(2H)-one 1,1-dioxide], C(10)H(9)NO(4)S, the benzo­thia­zole unit is essentially planar [maximum deviation = 0.0490 (9) Å for the S atom] and the oxopropyl group is inclined at an angle 75.61 (8)° with respect to its mean pla...

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Autores principales: Ahmad, Matloob, Siddiqui, Hamid Latif, Azam, Muhammad, Siddiqui, Waseeq Ahmad, Parvez, Masood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970051/
https://www.ncbi.nlm.nih.gov/pubmed/21577589
http://dx.doi.org/10.1107/S1600536809030773
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author Ahmad, Matloob
Siddiqui, Hamid Latif
Azam, Muhammad
Siddiqui, Waseeq Ahmad
Parvez, Masood
author_facet Ahmad, Matloob
Siddiqui, Hamid Latif
Azam, Muhammad
Siddiqui, Waseeq Ahmad
Parvez, Masood
author_sort Ahmad, Matloob
collection PubMed
description In the title compound [systematic name: 2-(2-oxoprop­yl)-1,2-benzothia­zol-3(2H)-one 1,1-dioxide], C(10)H(9)NO(4)S, the benzo­thia­zole unit is essentially planar [maximum deviation = 0.0490 (9) Å for the S atom] and the oxopropyl group is inclined at an angle 75.61 (8)° with respect to its mean plane. In the crystal, mol­ecules are held together by weak inter­molecular C—H⋯O non-classical hydrogen bonds, resulting in centrosymmetric dimeric units, forming 14-membered ring systems which may be described as R (2) (2)(14) ring motifs. Moreover, mol­ecules lying about inversion centers show π–π inter­actions, with centroid–centroid separations between the benzene rings of 3.676 (2) Å.
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spelling pubmed-29700512010-12-30 N-Acetonylsaccharin Ahmad, Matloob Siddiqui, Hamid Latif Azam, Muhammad Siddiqui, Waseeq Ahmad Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound [systematic name: 2-(2-oxoprop­yl)-1,2-benzothia­zol-3(2H)-one 1,1-dioxide], C(10)H(9)NO(4)S, the benzo­thia­zole unit is essentially planar [maximum deviation = 0.0490 (9) Å for the S atom] and the oxopropyl group is inclined at an angle 75.61 (8)° with respect to its mean plane. In the crystal, mol­ecules are held together by weak inter­molecular C—H⋯O non-classical hydrogen bonds, resulting in centrosymmetric dimeric units, forming 14-membered ring systems which may be described as R (2) (2)(14) ring motifs. Moreover, mol­ecules lying about inversion centers show π–π inter­actions, with centroid–centroid separations between the benzene rings of 3.676 (2) Å. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970051/ /pubmed/21577589 http://dx.doi.org/10.1107/S1600536809030773 Text en © Ahmad et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ahmad, Matloob
Siddiqui, Hamid Latif
Azam, Muhammad
Siddiqui, Waseeq Ahmad
Parvez, Masood
N-Acetonylsaccharin
title N-Acetonylsaccharin
title_full N-Acetonylsaccharin
title_fullStr N-Acetonylsaccharin
title_full_unstemmed N-Acetonylsaccharin
title_short N-Acetonylsaccharin
title_sort n-acetonylsaccharin
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970051/
https://www.ncbi.nlm.nih.gov/pubmed/21577589
http://dx.doi.org/10.1107/S1600536809030773
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