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5-Fluoro-2-(4-iodophenyl)-3-methylsulfinyl-1-benzofuran
In the title compound, C(15)H(10)FIO(2)S, the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The 4-iodophenyl ring is rotated out of the benzofuran plane by a dihedral angle of 39.4 (1)°. The crystal structure is st...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970055/ https://www.ncbi.nlm.nih.gov/pubmed/21577530 http://dx.doi.org/10.1107/S1600536809030992 |
Sumario: | In the title compound, C(15)H(10)FIO(2)S, the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The 4-iodophenyl ring is rotated out of the benzofuran plane by a dihedral angle of 39.4 (1)°. The crystal structure is stabilized by an intermolecular C—H⋯O hydrogen bond and an I⋯O halogen bond [3.055 (2) Å]. The crystal structure also exhibits an intermolecular C—H⋯π interaction between the methyl H atom and the 4-iodophenyl ring of an adjacent benzofuran molecule, and aromatic π–π interactions between the benzene rings of neighbouring benzofuran systems [centroid–centroid distance = 3.558 (3) Å]. |
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