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Dichloridobis(5-heptyl-1,3,4-thia­diazol-2-amine-κN (3))zinc(II)

In the title compound, [ZnCl(2)(C(9)H(17)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-heptyl-1,3,4-thia­diazol-2-amine ligands and two Cl atoms in a distorted tetra­hedral geometry. The thia­diazole rings are oriented at a dihedral angle of 84.87 (4)°. Intra­molecular N—...

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Detalles Bibliográficos
Autores principales: Wang, Peng, Wan, Rong, Wang, Bin, Han, Feng, Wang, Yao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970057/
https://www.ncbi.nlm.nih.gov/pubmed/21577437
http://dx.doi.org/10.1107/S1600536809032073
Descripción
Sumario:In the title compound, [ZnCl(2)(C(9)H(17)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-heptyl-1,3,4-thia­diazol-2-amine ligands and two Cl atoms in a distorted tetra­hedral geometry. The thia­diazole rings are oriented at a dihedral angle of 84.87 (4)°. Intra­molecular N—H⋯Cl inter­actions result in the formation of two six-membered rings having envelope and planar conformations. In the crystal structure, inter­molecular N—H⋯N and N—H⋯Cl inter­actions link the mol­ecules into a three-dimensional network. π–π contacts between thia­diazole rings [centroid–centroid distance = 3.602 (1) Å] may further stabilize the structure.