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Dichloridobis(5-heptyl-1,3,4-thiadiazol-2-amine-κN (3))zinc(II)
In the title compound, [ZnCl(2)(C(9)H(17)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-heptyl-1,3,4-thiadiazol-2-amine ligands and two Cl atoms in a distorted tetrahedral geometry. The thiadiazole rings are oriented at a dihedral angle of 84.87 (4)°. Intramolecular N—...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970057/ https://www.ncbi.nlm.nih.gov/pubmed/21577437 http://dx.doi.org/10.1107/S1600536809032073 |
Sumario: | In the title compound, [ZnCl(2)(C(9)H(17)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-heptyl-1,3,4-thiadiazol-2-amine ligands and two Cl atoms in a distorted tetrahedral geometry. The thiadiazole rings are oriented at a dihedral angle of 84.87 (4)°. Intramolecular N—H⋯Cl interactions result in the formation of two six-membered rings having envelope and planar conformations. In the crystal structure, intermolecular N—H⋯N and N—H⋯Cl interactions link the molecules into a three-dimensional network. π–π contacts between thiadiazole rings [centroid–centroid distance = 3.602 (1) Å] may further stabilize the structure. |
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