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Dichloridobis(5-heptyl-1,3,4-thiadiazol-2-amine-κN (3))zinc(II)
In the title compound, [ZnCl(2)(C(9)H(17)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-heptyl-1,3,4-thiadiazol-2-amine ligands and two Cl atoms in a distorted tetrahedral geometry. The thiadiazole rings are oriented at a dihedral angle of 84.87 (4)°. Intramolecular N—...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970057/ https://www.ncbi.nlm.nih.gov/pubmed/21577437 http://dx.doi.org/10.1107/S1600536809032073 |
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author | Wang, Peng Wan, Rong Wang, Bin Han, Feng Wang, Yao |
author_facet | Wang, Peng Wan, Rong Wang, Bin Han, Feng Wang, Yao |
author_sort | Wang, Peng |
collection | PubMed |
description | In the title compound, [ZnCl(2)(C(9)H(17)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-heptyl-1,3,4-thiadiazol-2-amine ligands and two Cl atoms in a distorted tetrahedral geometry. The thiadiazole rings are oriented at a dihedral angle of 84.87 (4)°. Intramolecular N—H⋯Cl interactions result in the formation of two six-membered rings having envelope and planar conformations. In the crystal structure, intermolecular N—H⋯N and N—H⋯Cl interactions link the molecules into a three-dimensional network. π–π contacts between thiadiazole rings [centroid–centroid distance = 3.602 (1) Å] may further stabilize the structure. |
format | Text |
id | pubmed-2970057 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29700572010-12-30 Dichloridobis(5-heptyl-1,3,4-thiadiazol-2-amine-κN (3))zinc(II) Wang, Peng Wan, Rong Wang, Bin Han, Feng Wang, Yao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(9)H(17)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-heptyl-1,3,4-thiadiazol-2-amine ligands and two Cl atoms in a distorted tetrahedral geometry. The thiadiazole rings are oriented at a dihedral angle of 84.87 (4)°. Intramolecular N—H⋯Cl interactions result in the formation of two six-membered rings having envelope and planar conformations. In the crystal structure, intermolecular N—H⋯N and N—H⋯Cl interactions link the molecules into a three-dimensional network. π–π contacts between thiadiazole rings [centroid–centroid distance = 3.602 (1) Å] may further stabilize the structure. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970057/ /pubmed/21577437 http://dx.doi.org/10.1107/S1600536809032073 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Peng Wan, Rong Wang, Bin Han, Feng Wang, Yao Dichloridobis(5-heptyl-1,3,4-thiadiazol-2-amine-κN (3))zinc(II) |
title | Dichloridobis(5-heptyl-1,3,4-thiadiazol-2-amine-κN
(3))zinc(II) |
title_full | Dichloridobis(5-heptyl-1,3,4-thiadiazol-2-amine-κN
(3))zinc(II) |
title_fullStr | Dichloridobis(5-heptyl-1,3,4-thiadiazol-2-amine-κN
(3))zinc(II) |
title_full_unstemmed | Dichloridobis(5-heptyl-1,3,4-thiadiazol-2-amine-κN
(3))zinc(II) |
title_short | Dichloridobis(5-heptyl-1,3,4-thiadiazol-2-amine-κN
(3))zinc(II) |
title_sort | dichloridobis(5-heptyl-1,3,4-thiadiazol-2-amine-κn
(3))zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970057/ https://www.ncbi.nlm.nih.gov/pubmed/21577437 http://dx.doi.org/10.1107/S1600536809032073 |
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