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Dichloridobis(5-heptyl-1,3,4-thia­diazol-2-amine-κN (3))zinc(II)

In the title compound, [ZnCl(2)(C(9)H(17)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-heptyl-1,3,4-thia­diazol-2-amine ligands and two Cl atoms in a distorted tetra­hedral geometry. The thia­diazole rings are oriented at a dihedral angle of 84.87 (4)°. Intra­molecular N—...

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Detalles Bibliográficos
Autores principales: Wang, Peng, Wan, Rong, Wang, Bin, Han, Feng, Wang, Yao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970057/
https://www.ncbi.nlm.nih.gov/pubmed/21577437
http://dx.doi.org/10.1107/S1600536809032073
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author Wang, Peng
Wan, Rong
Wang, Bin
Han, Feng
Wang, Yao
author_facet Wang, Peng
Wan, Rong
Wang, Bin
Han, Feng
Wang, Yao
author_sort Wang, Peng
collection PubMed
description In the title compound, [ZnCl(2)(C(9)H(17)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-heptyl-1,3,4-thia­diazol-2-amine ligands and two Cl atoms in a distorted tetra­hedral geometry. The thia­diazole rings are oriented at a dihedral angle of 84.87 (4)°. Intra­molecular N—H⋯Cl inter­actions result in the formation of two six-membered rings having envelope and planar conformations. In the crystal structure, inter­molecular N—H⋯N and N—H⋯Cl inter­actions link the mol­ecules into a three-dimensional network. π–π contacts between thia­diazole rings [centroid–centroid distance = 3.602 (1) Å] may further stabilize the structure.
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spelling pubmed-29700572010-12-30 Dichloridobis(5-heptyl-1,3,4-thia­diazol-2-amine-κN (3))zinc(II) Wang, Peng Wan, Rong Wang, Bin Han, Feng Wang, Yao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(9)H(17)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-heptyl-1,3,4-thia­diazol-2-amine ligands and two Cl atoms in a distorted tetra­hedral geometry. The thia­diazole rings are oriented at a dihedral angle of 84.87 (4)°. Intra­molecular N—H⋯Cl inter­actions result in the formation of two six-membered rings having envelope and planar conformations. In the crystal structure, inter­molecular N—H⋯N and N—H⋯Cl inter­actions link the mol­ecules into a three-dimensional network. π–π contacts between thia­diazole rings [centroid–centroid distance = 3.602 (1) Å] may further stabilize the structure. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970057/ /pubmed/21577437 http://dx.doi.org/10.1107/S1600536809032073 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Peng
Wan, Rong
Wang, Bin
Han, Feng
Wang, Yao
Dichloridobis(5-heptyl-1,3,4-thia­diazol-2-amine-κN (3))zinc(II)
title Dichloridobis(5-heptyl-1,3,4-thia­diazol-2-amine-κN (3))zinc(II)
title_full Dichloridobis(5-heptyl-1,3,4-thia­diazol-2-amine-κN (3))zinc(II)
title_fullStr Dichloridobis(5-heptyl-1,3,4-thia­diazol-2-amine-κN (3))zinc(II)
title_full_unstemmed Dichloridobis(5-heptyl-1,3,4-thia­diazol-2-amine-κN (3))zinc(II)
title_short Dichloridobis(5-heptyl-1,3,4-thia­diazol-2-amine-κN (3))zinc(II)
title_sort dichloridobis(5-heptyl-1,3,4-thia­diazol-2-amine-κn (3))zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970057/
https://www.ncbi.nlm.nih.gov/pubmed/21577437
http://dx.doi.org/10.1107/S1600536809032073
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