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Diaqua­bis[4-(dimethyl­amino)benzoato-κO](isonicotinamide-κN (1))manganese(II)

The title Mn(II) complex, [Mn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(H(2)O)(2)], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water mol­ecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms...

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Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Aybirdi, Özgür, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970058/
https://www.ncbi.nlm.nih.gov/pubmed/21577401
http://dx.doi.org/10.1107/S1600536809027093
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author Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description The title Mn(II) complex, [Mn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(H(2)O)(2)], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water mol­ecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial plane around the Mn atom form a highly distorted square-planar arrangement, while the distorted octa­hedral coordination geometry is completed by the N atom of the INA ligand and the O atom of the second water mol­ecule in the axial positions. In the crystal structure, strong inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to (010). Two weak C—H⋯π inter­actions are also found.
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spelling pubmed-29700582010-12-30 Diaqua­bis[4-(dimethyl­amino)benzoato-κO](isonicotinamide-κN (1))manganese(II) Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Mn(II) complex, [Mn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(H(2)O)(2)], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water mol­ecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial plane around the Mn atom form a highly distorted square-planar arrangement, while the distorted octa­hedral coordination geometry is completed by the N atom of the INA ligand and the O atom of the second water mol­ecule in the axial positions. In the crystal structure, strong inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to (010). Two weak C—H⋯π inter­actions are also found. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970058/ /pubmed/21577401 http://dx.doi.org/10.1107/S1600536809027093 Text en © Hökelek* et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
Diaqua­bis[4-(dimethyl­amino)benzoato-κO](isonicotinamide-κN (1))manganese(II)
title Diaqua­bis[4-(dimethyl­amino)benzoato-κO](isonicotinamide-κN (1))manganese(II)
title_full Diaqua­bis[4-(dimethyl­amino)benzoato-κO](isonicotinamide-κN (1))manganese(II)
title_fullStr Diaqua­bis[4-(dimethyl­amino)benzoato-κO](isonicotinamide-κN (1))manganese(II)
title_full_unstemmed Diaqua­bis[4-(dimethyl­amino)benzoato-κO](isonicotinamide-κN (1))manganese(II)
title_short Diaqua­bis[4-(dimethyl­amino)benzoato-κO](isonicotinamide-κN (1))manganese(II)
title_sort diaqua­bis[4-(dimethyl­amino)benzoato-κo](isonicotinamide-κn (1))manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970058/
https://www.ncbi.nlm.nih.gov/pubmed/21577401
http://dx.doi.org/10.1107/S1600536809027093
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