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Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN (1))manganese(II)
The title Mn(II) complex, [Mn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(H(2)O)(2)], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water molecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970058/ https://www.ncbi.nlm.nih.gov/pubmed/21577401 http://dx.doi.org/10.1107/S1600536809027093 |
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author | Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_facet | Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_sort | Hökelek, Tuncer |
collection | PubMed |
description | The title Mn(II) complex, [Mn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(H(2)O)(2)], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water molecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial plane around the Mn atom form a highly distorted square-planar arrangement, while the distorted octahedral coordination geometry is completed by the N atom of the INA ligand and the O atom of the second water molecule in the axial positions. In the crystal structure, strong intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (010). Two weak C—H⋯π interactions are also found. |
format | Text |
id | pubmed-2970058 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29700582010-12-30 Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN (1))manganese(II) Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Mn(II) complex, [Mn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(H(2)O)(2)], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water molecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial plane around the Mn atom form a highly distorted square-planar arrangement, while the distorted octahedral coordination geometry is completed by the N atom of the INA ligand and the O atom of the second water molecule in the axial positions. In the crystal structure, strong intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (010). Two weak C—H⋯π interactions are also found. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970058/ /pubmed/21577401 http://dx.doi.org/10.1107/S1600536809027093 Text en © Hökelek* et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN (1))manganese(II) |
title | Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN
(1))manganese(II) |
title_full | Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN
(1))manganese(II) |
title_fullStr | Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN
(1))manganese(II) |
title_full_unstemmed | Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN
(1))manganese(II) |
title_short | Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN
(1))manganese(II) |
title_sort | diaquabis[4-(dimethylamino)benzoato-κo](isonicotinamide-κn
(1))manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970058/ https://www.ncbi.nlm.nih.gov/pubmed/21577401 http://dx.doi.org/10.1107/S1600536809027093 |
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