Diaqua­(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) tetra­cyanidonickelate(II)

In the title complex, [Ni(C(16)H(36)N(4))(H(2)O)(2)][Ni(CN)(4)], the [Ni(teta)(H(2)O)(2)](2+) cations (teta = 5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne) and [Ni(CN)(4)](2−) anions are arranged in an alternating fashion through electrostatic and N—H⋯N and O—H⋯N hydrogen-bonding...

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Detalles Bibliográficos
Autores principales: Zhang, Qian, Shen, Xiao-Ping, Zhou, Hu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970059/
https://www.ncbi.nlm.nih.gov/pubmed/21577476
http://dx.doi.org/10.1107/S1600536809033820
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author Zhang, Qian
Shen, Xiao-Ping
Zhou, Hu
author_facet Zhang, Qian
Shen, Xiao-Ping
Zhou, Hu
author_sort Zhang, Qian
collection PubMed
description In the title complex, [Ni(C(16)H(36)N(4))(H(2)O)(2)][Ni(CN)(4)], the [Ni(teta)(H(2)O)(2)](2+) cations (teta = 5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne) and [Ni(CN)(4)](2−) anions are arranged in an alternating fashion through electrostatic and N—H⋯N and O—H⋯N hydrogen-bonding inter­actions, forming a two-dimensional layered structure. Adjacent layers are linked through weak van der Waals inter­actions, resulting in a three-dimensional supra­molecular network.
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spelling pubmed-29700592010-12-30 Diaqua­(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) tetra­cyanidonickelate(II) Zhang, Qian Shen, Xiao-Ping Zhou, Hu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(16)H(36)N(4))(H(2)O)(2)][Ni(CN)(4)], the [Ni(teta)(H(2)O)(2)](2+) cations (teta = 5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne) and [Ni(CN)(4)](2−) anions are arranged in an alternating fashion through electrostatic and N—H⋯N and O—H⋯N hydrogen-bonding inter­actions, forming a two-dimensional layered structure. Adjacent layers are linked through weak van der Waals inter­actions, resulting in a three-dimensional supra­molecular network. International Union of Crystallography 2009-08-29 /pmc/articles/PMC2970059/ /pubmed/21577476 http://dx.doi.org/10.1107/S1600536809033820 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Qian
Shen, Xiao-Ping
Zhou, Hu
Diaqua­(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) tetra­cyanidonickelate(II)
title Diaqua­(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) tetra­cyanidonickelate(II)
title_full Diaqua­(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) tetra­cyanidonickelate(II)
title_fullStr Diaqua­(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) tetra­cyanidonickelate(II)
title_full_unstemmed Diaqua­(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) tetra­cyanidonickelate(II)
title_short Diaqua­(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) tetra­cyanidonickelate(II)
title_sort diaqua­(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(ii) tetra­cyanidonickelate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970059/
https://www.ncbi.nlm.nih.gov/pubmed/21577476
http://dx.doi.org/10.1107/S1600536809033820
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AT zhouhu diaqua557121214hexamethyl14811tetraazacyclotetradecanenickeliitetracyanidonickelateii

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