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Memanti­nium chloride 0.1-hydrate

The crystal structure of the title compound, C(12)H(22)N(+)·Cl(−)·0.1H(2)O, consists of (3,5-dimethyl-1-adamantyl)ammonium chloride (memanti­nium chloride) and uncoordinated water mol­ecules. The four six-membered rings of the memanti­nium cation assume typical chair conformations. The Cl(−) counter...

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Detalles Bibliográficos
Autores principales: Lou, Wei-Jian, Hu, Xiu-Rong, Gu, Jian-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970061/
https://www.ncbi.nlm.nih.gov/pubmed/21577595
http://dx.doi.org/10.1107/S1600536809031791
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author Lou, Wei-Jian
Hu, Xiu-Rong
Gu, Jian-Ming
author_facet Lou, Wei-Jian
Hu, Xiu-Rong
Gu, Jian-Ming
author_sort Lou, Wei-Jian
collection PubMed
description The crystal structure of the title compound, C(12)H(22)N(+)·Cl(−)·0.1H(2)O, consists of (3,5-dimethyl-1-adamantyl)ammonium chloride (memanti­nium chloride) and uncoordinated water mol­ecules. The four six-membered rings of the memanti­nium cation assume typical chair conformations. The Cl(−) counter-anion links with the memanti­nium cation via N—H⋯Cl hydrogen bonding, forming channels where the disordered crystal water molecules are located. The O atom of the water mol­ecule is located on a threefold rotation axis, its two H atoms symmetrically distributed over six sites; the water mol­ecule links with the Cl(−) anions via O—H⋯Cl hydrogen bonding.
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spelling pubmed-29700612010-12-30 Memanti­nium chloride 0.1-hydrate Lou, Wei-Jian Hu, Xiu-Rong Gu, Jian-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(12)H(22)N(+)·Cl(−)·0.1H(2)O, consists of (3,5-dimethyl-1-adamantyl)ammonium chloride (memanti­nium chloride) and uncoordinated water mol­ecules. The four six-membered rings of the memanti­nium cation assume typical chair conformations. The Cl(−) counter-anion links with the memanti­nium cation via N—H⋯Cl hydrogen bonding, forming channels where the disordered crystal water molecules are located. The O atom of the water mol­ecule is located on a threefold rotation axis, its two H atoms symmetrically distributed over six sites; the water mol­ecule links with the Cl(−) anions via O—H⋯Cl hydrogen bonding. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970061/ /pubmed/21577595 http://dx.doi.org/10.1107/S1600536809031791 Text en © Lou et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lou, Wei-Jian
Hu, Xiu-Rong
Gu, Jian-Ming
Memanti­nium chloride 0.1-hydrate
title Memanti­nium chloride 0.1-hydrate
title_full Memanti­nium chloride 0.1-hydrate
title_fullStr Memanti­nium chloride 0.1-hydrate
title_full_unstemmed Memanti­nium chloride 0.1-hydrate
title_short Memanti­nium chloride 0.1-hydrate
title_sort memanti­nium chloride 0.1-hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970061/
https://www.ncbi.nlm.nih.gov/pubmed/21577595
http://dx.doi.org/10.1107/S1600536809031791
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