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Bis[μ-2-(2-pyridylmethyl­amino­meth­yl)phenolato]-κ(4) N,N′,O:O;κ(4) O:N,N′,O-bis­[(thio­cyanato-κN)copper(II)]

The centrosymmetric binuclear complex, [Cu(2)(C(13)H(13)N(2)O)(2)(NCS)(2)], formed via phenolate oxygen bridges, involves the Cu(II) atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu⋯Cu separation of 3.2281 (3) Å is observed. The in-plane Cu—O(phenolate) distance [1.9342 (8) Å...

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Autores principales: Assey, Gervas E., Tesema, Yohannes, Yisgedu, Teshome, Gultneh, Yilma, Butcher, Ray J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970067/
https://www.ncbi.nlm.nih.gov/pubmed/21577463
http://dx.doi.org/10.1107/S1600536809031742
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author Assey, Gervas E.
Tesema, Yohannes
Yisgedu, Teshome
Gultneh, Yilma
Butcher, Ray J.
author_facet Assey, Gervas E.
Tesema, Yohannes
Yisgedu, Teshome
Gultneh, Yilma
Butcher, Ray J.
author_sort Assey, Gervas E.
collection PubMed
description The centrosymmetric binuclear complex, [Cu(2)(C(13)H(13)N(2)O)(2)(NCS)(2)], formed via phenolate oxygen bridges, involves the Cu(II) atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu⋯Cu separation of 3.2281 (3) Å is observed. The in-plane Cu—O(phenolate) distance [1.9342 (8) Å] is shorter than the axial distance [2.252 (8) Å]. The Cu—N(amine) and Cu—N(py) distances are similar [2.0095 (10) and 2.0192 (10) Å, respectively]. The Cu—N(thio­cyanate) distance [1.9678 (11) Å] is in the range found for Cu—N distances in previously determined structures containing coordinated thio­cyanate anions. There is an inter­molecular hydrogen bond between the amine H atom and the S atom of a coordinated thio­cyanate anion.
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spelling pubmed-29700672010-12-30 Bis[μ-2-(2-pyridylmethyl­amino­meth­yl)phenolato]-κ(4) N,N′,O:O;κ(4) O:N,N′,O-bis­[(thio­cyanato-κN)copper(II)] Assey, Gervas E. Tesema, Yohannes Yisgedu, Teshome Gultneh, Yilma Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The centrosymmetric binuclear complex, [Cu(2)(C(13)H(13)N(2)O)(2)(NCS)(2)], formed via phenolate oxygen bridges, involves the Cu(II) atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu⋯Cu separation of 3.2281 (3) Å is observed. The in-plane Cu—O(phenolate) distance [1.9342 (8) Å] is shorter than the axial distance [2.252 (8) Å]. The Cu—N(amine) and Cu—N(py) distances are similar [2.0095 (10) and 2.0192 (10) Å, respectively]. The Cu—N(thio­cyanate) distance [1.9678 (11) Å] is in the range found for Cu—N distances in previously determined structures containing coordinated thio­cyanate anions. There is an inter­molecular hydrogen bond between the amine H atom and the S atom of a coordinated thio­cyanate anion. International Union of Crystallography 2009-08-22 /pmc/articles/PMC2970067/ /pubmed/21577463 http://dx.doi.org/10.1107/S1600536809031742 Text en © Assey et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Assey, Gervas E.
Tesema, Yohannes
Yisgedu, Teshome
Gultneh, Yilma
Butcher, Ray J.
Bis[μ-2-(2-pyridylmethyl­amino­meth­yl)phenolato]-κ(4) N,N′,O:O;κ(4) O:N,N′,O-bis­[(thio­cyanato-κN)copper(II)]
title Bis[μ-2-(2-pyridylmethyl­amino­meth­yl)phenolato]-κ(4) N,N′,O:O;κ(4) O:N,N′,O-bis­[(thio­cyanato-κN)copper(II)]
title_full Bis[μ-2-(2-pyridylmethyl­amino­meth­yl)phenolato]-κ(4) N,N′,O:O;κ(4) O:N,N′,O-bis­[(thio­cyanato-κN)copper(II)]
title_fullStr Bis[μ-2-(2-pyridylmethyl­amino­meth­yl)phenolato]-κ(4) N,N′,O:O;κ(4) O:N,N′,O-bis­[(thio­cyanato-κN)copper(II)]
title_full_unstemmed Bis[μ-2-(2-pyridylmethyl­amino­meth­yl)phenolato]-κ(4) N,N′,O:O;κ(4) O:N,N′,O-bis­[(thio­cyanato-κN)copper(II)]
title_short Bis[μ-2-(2-pyridylmethyl­amino­meth­yl)phenolato]-κ(4) N,N′,O:O;κ(4) O:N,N′,O-bis­[(thio­cyanato-κN)copper(II)]
title_sort bis[μ-2-(2-pyridylmethyl­amino­meth­yl)phenolato]-κ(4) n,n′,o:o;κ(4) o:n,n′,o-bis­[(thio­cyanato-κn)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970067/
https://www.ncbi.nlm.nih.gov/pubmed/21577463
http://dx.doi.org/10.1107/S1600536809031742
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