(2RS)-3-Hydr­oxy-2-methyl-2-(2-pyrid­yl)imidazolidine-4-one

The title structure, C(9)H(11)N(3)O(2), is a racemate. The chiral centre is situated at the N—C—N C atom of the imidazolidine ring. The inter­planar angle between the mean planes of the pyridine and imidazolidine rings is 89.41 (5)°. The methyl group is in a trans position with respect to the pyridi...

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Autores principales: Iskenderov, Turganbay S., Golenya, Irina A., Gumienna-Kontecka, Elźbieta, Fritsky, Igor O., Prisyazhnaya, Elena V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970069/
https://www.ncbi.nlm.nih.gov/pubmed/21577537
http://dx.doi.org/10.1107/S1600536809030840
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author Iskenderov, Turganbay S.
Golenya, Irina A.
Gumienna-Kontecka, Elźbieta
Fritsky, Igor O.
Prisyazhnaya, Elena V.
author_facet Iskenderov, Turganbay S.
Golenya, Irina A.
Gumienna-Kontecka, Elźbieta
Fritsky, Igor O.
Prisyazhnaya, Elena V.
author_sort Iskenderov, Turganbay S.
collection PubMed
description The title structure, C(9)H(11)N(3)O(2), is a racemate. The chiral centre is situated at the N—C—N C atom of the imidazolidine ring. The inter­planar angle between the mean planes of the pyridine and imidazolidine rings is 89.41 (5)°. The methyl group is in a trans position with respect to the pyridine N atom. In the crystal, the mol­ecules are arranged in zigzag layers parallel to the b axis. The mol­ecules within the layers are inter­connected by strong O—H⋯N and weak N—H⋯O hydrogen bonds; the former take place between OH groups and amine N atoms and the latter between the amine N atom and the carbonyl O atom. In addition, C—H⋯O inter­actions are also present.
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spelling pubmed-29700692010-12-30 (2RS)-3-Hydr­oxy-2-methyl-2-(2-pyrid­yl)imidazolidine-4-one Iskenderov, Turganbay S. Golenya, Irina A. Gumienna-Kontecka, Elźbieta Fritsky, Igor O. Prisyazhnaya, Elena V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title structure, C(9)H(11)N(3)O(2), is a racemate. The chiral centre is situated at the N—C—N C atom of the imidazolidine ring. The inter­planar angle between the mean planes of the pyridine and imidazolidine rings is 89.41 (5)°. The methyl group is in a trans position with respect to the pyridine N atom. In the crystal, the mol­ecules are arranged in zigzag layers parallel to the b axis. The mol­ecules within the layers are inter­connected by strong O—H⋯N and weak N—H⋯O hydrogen bonds; the former take place between OH groups and amine N atoms and the latter between the amine N atom and the carbonyl O atom. In addition, C—H⋯O inter­actions are also present. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970069/ /pubmed/21577537 http://dx.doi.org/10.1107/S1600536809030840 Text en © Iskenderov et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Iskenderov, Turganbay S.
Golenya, Irina A.
Gumienna-Kontecka, Elźbieta
Fritsky, Igor O.
Prisyazhnaya, Elena V.
(2RS)-3-Hydr­oxy-2-methyl-2-(2-pyrid­yl)imidazolidine-4-one
title (2RS)-3-Hydr­oxy-2-methyl-2-(2-pyrid­yl)imidazolidine-4-one
title_full (2RS)-3-Hydr­oxy-2-methyl-2-(2-pyrid­yl)imidazolidine-4-one
title_fullStr (2RS)-3-Hydr­oxy-2-methyl-2-(2-pyrid­yl)imidazolidine-4-one
title_full_unstemmed (2RS)-3-Hydr­oxy-2-methyl-2-(2-pyrid­yl)imidazolidine-4-one
title_short (2RS)-3-Hydr­oxy-2-methyl-2-(2-pyrid­yl)imidazolidine-4-one
title_sort (2rs)-3-hydr­oxy-2-methyl-2-(2-pyrid­yl)imidazolidine-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970069/
https://www.ncbi.nlm.nih.gov/pubmed/21577537
http://dx.doi.org/10.1107/S1600536809030840
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