1-Dibromo­methyl-4-meth­oxy-2-nitro­benzene

The asymmetric unit of the title compound, C(8)H(7)Br(2)NO(3), comprises two crystallographically independent mol­ecules (A and B). The nitro groups are twisted from the attached benzene rings, making dihedral angles of 39.26 (9) and 35.90 (9)° in mol­ecules A and B, respectively. In each mol­ecule,...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Chandrakantha, B., Isloor, Arun M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970072/
https://www.ncbi.nlm.nih.gov/pubmed/21577597
http://dx.doi.org/10.1107/S1600536809031833
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author Fun, Hoong-Kun
Goh, Jia Hao
Chandrakantha, B.
Isloor, Arun M.
author_facet Fun, Hoong-Kun
Goh, Jia Hao
Chandrakantha, B.
Isloor, Arun M.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(8)H(7)Br(2)NO(3), comprises two crystallographically independent mol­ecules (A and B). The nitro groups are twisted from the attached benzene rings, making dihedral angles of 39.26 (9) and 35.90 (9)° in mol­ecules A and B, respectively. In each mol­ecule, the dibromo­methyl group is orientated in such a way that the two Br atoms are tilted away from the benzene ring. An inter­esting features of the crystal structure is the two short Br⋯Br inter­actions which, together with inter­molecular C—H⋯O hydrogen bonds, link the mol­ecules into an extended three-dimensional network. The crystal structure is further stabilized by weak C—H⋯π inter­actions.
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spelling pubmed-29700722010-12-30 1-Dibromo­methyl-4-meth­oxy-2-nitro­benzene Fun, Hoong-Kun Goh, Jia Hao Chandrakantha, B. Isloor, Arun M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(8)H(7)Br(2)NO(3), comprises two crystallographically independent mol­ecules (A and B). The nitro groups are twisted from the attached benzene rings, making dihedral angles of 39.26 (9) and 35.90 (9)° in mol­ecules A and B, respectively. In each mol­ecule, the dibromo­methyl group is orientated in such a way that the two Br atoms are tilted away from the benzene ring. An inter­esting features of the crystal structure is the two short Br⋯Br inter­actions which, together with inter­molecular C—H⋯O hydrogen bonds, link the mol­ecules into an extended three-dimensional network. The crystal structure is further stabilized by weak C—H⋯π inter­actions. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970072/ /pubmed/21577597 http://dx.doi.org/10.1107/S1600536809031833 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Goh, Jia Hao
Chandrakantha, B.
Isloor, Arun M.
1-Dibromo­methyl-4-meth­oxy-2-nitro­benzene
title 1-Dibromo­methyl-4-meth­oxy-2-nitro­benzene
title_full 1-Dibromo­methyl-4-meth­oxy-2-nitro­benzene
title_fullStr 1-Dibromo­methyl-4-meth­oxy-2-nitro­benzene
title_full_unstemmed 1-Dibromo­methyl-4-meth­oxy-2-nitro­benzene
title_short 1-Dibromo­methyl-4-meth­oxy-2-nitro­benzene
title_sort 1-dibromo­methyl-4-meth­oxy-2-nitro­benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970072/
https://www.ncbi.nlm.nih.gov/pubmed/21577597
http://dx.doi.org/10.1107/S1600536809031833
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AT gohjiahao 1dibromomethyl4methoxy2nitrobenzene
AT chandrakanthab 1dibromomethyl4methoxy2nitrobenzene
AT isloorarunm 1dibromomethyl4methoxy2nitrobenzene

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