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Tetrapyridinebis(trichloroacetato)nickel(II)
The title compound, [Ni(C(2)Cl(3)O(2))(2)(C(5)H(5)N)(4)], was prepared by the reaction of pyridine and trichloroacetatonickel(II) in ethanol solution at room temperature. The Ni(II) atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination made up of four N at...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970073/ https://www.ncbi.nlm.nih.gov/pubmed/21577404 http://dx.doi.org/10.1107/S1600536809030025 |
| _version_ | 1782190338506489856 |
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| author | Li, Li-Min Jian, Fang-Fang Ren, Xiao-Yan |
| author_facet | Li, Li-Min Jian, Fang-Fang Ren, Xiao-Yan |
| author_sort | Li, Li-Min |
| collection | PubMed |
| description | The title compound, [Ni(C(2)Cl(3)O(2))(2)(C(5)H(5)N)(4)], was prepared by the reaction of pyridine and trichloroacetatonickel(II) in ethanol solution at room temperature. The Ni(II) atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination made up of four N atoms of the pyridine ligands and two O atoms of trichloroacetate anions. The molecular structure and packing are stabilized by intra- and intermolecular C—H⋯O hydrogen-bonding interactions. |
| format | Text |
| id | pubmed-2970073 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29700732010-12-30 Tetrapyridinebis(trichloroacetato)nickel(II) Li, Li-Min Jian, Fang-Fang Ren, Xiao-Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(2)Cl(3)O(2))(2)(C(5)H(5)N)(4)], was prepared by the reaction of pyridine and trichloroacetatonickel(II) in ethanol solution at room temperature. The Ni(II) atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination made up of four N atoms of the pyridine ligands and two O atoms of trichloroacetate anions. The molecular structure and packing are stabilized by intra- and intermolecular C—H⋯O hydrogen-bonding interactions. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970073/ /pubmed/21577404 http://dx.doi.org/10.1107/S1600536809030025 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Li-Min Jian, Fang-Fang Ren, Xiao-Yan Tetrapyridinebis(trichloroacetato)nickel(II) |
| title | Tetrapyridinebis(trichloroacetato)nickel(II) |
| title_full | Tetrapyridinebis(trichloroacetato)nickel(II) |
| title_fullStr | Tetrapyridinebis(trichloroacetato)nickel(II) |
| title_full_unstemmed | Tetrapyridinebis(trichloroacetato)nickel(II) |
| title_short | Tetrapyridinebis(trichloroacetato)nickel(II) |
| title_sort | tetrapyridinebis(trichloroacetato)nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970073/ https://www.ncbi.nlm.nih.gov/pubmed/21577404 http://dx.doi.org/10.1107/S1600536809030025 |
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