Butane-1,4-diammonium bis­(pyridine-2-carboxyl­ate) monohydrate

The asymmetric unit of the title compound, C(4)H(14)N(2) (2+)·2C(6)H(4)NO(2) (−)·H(2)O, consists of half of a doubly protonated tetra­methyl­enediammonium dication, a pyridine-2-carboxyl­ate anion and half of a solvent water mol­ecule; the dication is located on a centre of inversion and a twofold r...

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Detalles Bibliográficos
Autores principales: Kim, Nam-Ho, Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970077/
https://www.ncbi.nlm.nih.gov/pubmed/21577560
http://dx.doi.org/10.1107/S1600536809031493
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author Kim, Nam-Ho
Ha, Kwang
author_facet Kim, Nam-Ho
Ha, Kwang
author_sort Kim, Nam-Ho
collection PubMed
description The asymmetric unit of the title compound, C(4)H(14)N(2) (2+)·2C(6)H(4)NO(2) (−)·H(2)O, consists of half of a doubly protonated tetra­methyl­enediammonium dication, a pyridine-2-carboxyl­ate anion and half of a solvent water mol­ecule; the dication is located on a centre of inversion and a twofold rotation axis passes through the O atom of the water mol­ecule. The carboxyl­ate group of the anion appears to be delocalized on the basis of the C—O bond lengths. In the crystal structure, the components are linked by inter­molecular N—H⋯O, N—H⋯N and O—H⋯O hydrogen bonds.
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spelling pubmed-29700772010-12-30 Butane-1,4-diammonium bis­(pyridine-2-carboxyl­ate) monohydrate Kim, Nam-Ho Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(4)H(14)N(2) (2+)·2C(6)H(4)NO(2) (−)·H(2)O, consists of half of a doubly protonated tetra­methyl­enediammonium dication, a pyridine-2-carboxyl­ate anion and half of a solvent water mol­ecule; the dication is located on a centre of inversion and a twofold rotation axis passes through the O atom of the water mol­ecule. The carboxyl­ate group of the anion appears to be delocalized on the basis of the C—O bond lengths. In the crystal structure, the components are linked by inter­molecular N—H⋯O, N—H⋯N and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-08-15 /pmc/articles/PMC2970077/ /pubmed/21577560 http://dx.doi.org/10.1107/S1600536809031493 Text en © Kim and Ha 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kim, Nam-Ho
Ha, Kwang
Butane-1,4-diammonium bis­(pyridine-2-carboxyl­ate) monohydrate
title Butane-1,4-diammonium bis­(pyridine-2-carboxyl­ate) monohydrate
title_full Butane-1,4-diammonium bis­(pyridine-2-carboxyl­ate) monohydrate
title_fullStr Butane-1,4-diammonium bis­(pyridine-2-carboxyl­ate) monohydrate
title_full_unstemmed Butane-1,4-diammonium bis­(pyridine-2-carboxyl­ate) monohydrate
title_short Butane-1,4-diammonium bis­(pyridine-2-carboxyl­ate) monohydrate
title_sort butane-1,4-diammonium bis­(pyridine-2-carboxyl­ate) monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970077/
https://www.ncbi.nlm.nih.gov/pubmed/21577560
http://dx.doi.org/10.1107/S1600536809031493
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AT hakwang butane14diammoniumbispyridine2carboxylatemonohydrate

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