(E)-Methyl N′-(3-methoxy­benzyl­idene)hydrazinecarboxyl­ate

The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit which differ in the orientation of the meth­oxy group. Each independent mol­ecule adopts a trans configuration with respect to the C=N bond. In the crystal structure, mol­ecules are linked int...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Yu, Wen-Bo, Huang, Chun-Yu, Li, Wei-Wei, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970081/
https://www.ncbi.nlm.nih.gov/pubmed/21577641
http://dx.doi.org/10.1107/S1600536809033194
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author Lv, Lu-Ping
Yu, Wen-Bo
Huang, Chun-Yu
Li, Wei-Wei
Hu, Xian-Chao
author_facet Lv, Lu-Ping
Yu, Wen-Bo
Huang, Chun-Yu
Li, Wei-Wei
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit which differ in the orientation of the meth­oxy group. Each independent mol­ecule adopts a trans configuration with respect to the C=N bond. In the crystal structure, mol­ecules are linked into chains running along [001] by N—H⋯O and N—H⋯N hydrogen bonds. In addition, an inter­molecular C—H⋯π inter­action is observed.
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spelling pubmed-29700812010-12-30 (E)-Methyl N′-(3-methoxy­benzyl­idene)hydrazinecarboxyl­ate Lv, Lu-Ping Yu, Wen-Bo Huang, Chun-Yu Li, Wei-Wei Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit which differ in the orientation of the meth­oxy group. Each independent mol­ecule adopts a trans configuration with respect to the C=N bond. In the crystal structure, mol­ecules are linked into chains running along [001] by N—H⋯O and N—H⋯N hydrogen bonds. In addition, an inter­molecular C—H⋯π inter­action is observed. International Union of Crystallography 2009-08-26 /pmc/articles/PMC2970081/ /pubmed/21577641 http://dx.doi.org/10.1107/S1600536809033194 Text en © Lv et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Yu, Wen-Bo
Huang, Chun-Yu
Li, Wei-Wei
Hu, Xian-Chao
(E)-Methyl N′-(3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title (E)-Methyl N′-(3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title_full (E)-Methyl N′-(3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title_fullStr (E)-Methyl N′-(3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title_full_unstemmed (E)-Methyl N′-(3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title_short (E)-Methyl N′-(3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
title_sort (e)-methyl n′-(3-methoxy­benzyl­idene)hydrazinecarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970081/
https://www.ncbi.nlm.nih.gov/pubmed/21577641
http://dx.doi.org/10.1107/S1600536809033194
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AT liweiwei emethyln3methoxybenzylidenehydrazinecarboxylate
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