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trans-(Pyrimidine-2-thiol­ato-κ(2) N,S)[tris­(2-amino­ethyl)amine-κ(4) N,N′,N′′,N′′′]cobalt(III) chloride hexa­fluoridophosphate

In the title compound, [Co(C(4)H(3)N(2)S)(C(6)H(18)N(4))](Cl)PF(6), the Co(III) ion is coordinated by a tripod-like tetra­dentate ligand and a monoanionic N,S-bidentate ligand in an approximately octa­hedral CoN(4)OS geometry. The anionic S atom of the pyrimidine-2-thiol­ate (pymt) ligand is coordin...

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Detalles Bibliográficos
Autores principales: Fujihara, Keisuke, Yonemura, Toshiaki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970082/
https://www.ncbi.nlm.nih.gov/pubmed/21577467
http://dx.doi.org/10.1107/S1600536809032395