(E)-3-Bromo-N′-(4-methoxy­benzyl­idene)benzohydrazide methanol solvate

The title compound, C(15)H(13)BrN(2)O(2)·CH(3)OH, was synthesized by the reaction of 4-methoxy­benzaldehyde with an equimolar quantity of 3-bromo­benzohydrazide in methanol. The benzohydrazide mol­ecule displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings...

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Autor principal: Cao, Guo-Biao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970086/
https://www.ncbi.nlm.nih.gov/pubmed/21577504
http://dx.doi.org/10.1107/S1600536809030219
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author Cao, Guo-Biao
author_facet Cao, Guo-Biao
author_sort Cao, Guo-Biao
collection PubMed
description The title compound, C(15)H(13)BrN(2)O(2)·CH(3)OH, was synthesized by the reaction of 4-methoxy­benzaldehyde with an equimolar quantity of 3-bromo­benzohydrazide in methanol. The benzohydrazide mol­ecule displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 4.0 (2)°. The benzohydrazide and methanol mol­ecules are linked into a chain propagating along the b axis by O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds.
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spelling pubmed-29700862010-12-30 (E)-3-Bromo-N′-(4-methoxy­benzyl­idene)benzohydrazide methanol solvate Cao, Guo-Biao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(13)BrN(2)O(2)·CH(3)OH, was synthesized by the reaction of 4-methoxy­benzaldehyde with an equimolar quantity of 3-bromo­benzohydrazide in methanol. The benzohydrazide mol­ecule displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 4.0 (2)°. The benzohydrazide and methanol mol­ecules are linked into a chain propagating along the b axis by O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970086/ /pubmed/21577504 http://dx.doi.org/10.1107/S1600536809030219 Text en © Guo-Biao Cao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cao, Guo-Biao
(E)-3-Bromo-N′-(4-methoxy­benzyl­idene)benzohydrazide methanol solvate
title (E)-3-Bromo-N′-(4-methoxy­benzyl­idene)benzohydrazide methanol solvate
title_full (E)-3-Bromo-N′-(4-methoxy­benzyl­idene)benzohydrazide methanol solvate
title_fullStr (E)-3-Bromo-N′-(4-methoxy­benzyl­idene)benzohydrazide methanol solvate
title_full_unstemmed (E)-3-Bromo-N′-(4-methoxy­benzyl­idene)benzohydrazide methanol solvate
title_short (E)-3-Bromo-N′-(4-methoxy­benzyl­idene)benzohydrazide methanol solvate
title_sort (e)-3-bromo-n′-(4-methoxy­benzyl­idene)benzohydrazide methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970086/
https://www.ncbi.nlm.nih.gov/pubmed/21577504
http://dx.doi.org/10.1107/S1600536809030219
work_keys_str_mv AT caoguobiao e3bromon4methoxybenzylidenebenzohydrazidemethanolsolvate

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