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Bis[2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis­(per­chlorate) acetonitrile solvate

In the cation of the title compound, [Mn(C(11)H(13)N(5))(2)](ClO(4))(2)·CH(3)CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms...

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Autores principales: Shang, Shao-Ming, Ren, Chun-Xia, Wang, Xin, Lu, Lu-De, Yang, Xu-Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970088/
https://www.ncbi.nlm.nih.gov/pubmed/21577391
http://dx.doi.org/10.1107/S1600536809029195
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author Shang, Shao-Ming
Ren, Chun-Xia
Wang, Xin
Lu, Lu-De
Yang, Xu-Jie
author_facet Shang, Shao-Ming
Ren, Chun-Xia
Wang, Xin
Lu, Lu-De
Yang, Xu-Jie
author_sort Shang, Shao-Ming
collection PubMed
description In the cation of the title compound, [Mn(C(11)H(13)N(5))(2)](ClO(4))(2)·CH(3)CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms of the perchlorate anions are disordered with occupancies in the ratio 0.593 (10):0.407 (10). In the crystal, mol­ecules are stabilized by two N—H⋯O hydrogen bonds, forming zigzag chains along the a axis, which are further inter­connected by N—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distance = 3.50 (1) Å] into a three-dimensional network.
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spelling pubmed-29700882010-12-30 Bis[2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis­(per­chlorate) acetonitrile solvate Shang, Shao-Ming Ren, Chun-Xia Wang, Xin Lu, Lu-De Yang, Xu-Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Mn(C(11)H(13)N(5))(2)](ClO(4))(2)·CH(3)CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms of the perchlorate anions are disordered with occupancies in the ratio 0.593 (10):0.407 (10). In the crystal, mol­ecules are stabilized by two N—H⋯O hydrogen bonds, forming zigzag chains along the a axis, which are further inter­connected by N—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distance = 3.50 (1) Å] into a three-dimensional network. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970088/ /pubmed/21577391 http://dx.doi.org/10.1107/S1600536809029195 Text en © Shang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shang, Shao-Ming
Ren, Chun-Xia
Wang, Xin
Lu, Lu-De
Yang, Xu-Jie
Bis[2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis­(per­chlorate) acetonitrile solvate
title Bis[2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis­(per­chlorate) acetonitrile solvate
title_full Bis[2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis­(per­chlorate) acetonitrile solvate
title_fullStr Bis[2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis­(per­chlorate) acetonitrile solvate
title_full_unstemmed Bis[2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis­(per­chlorate) acetonitrile solvate
title_short Bis[2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis­(per­chlorate) acetonitrile solvate
title_sort bis[2,6-bis­(4,5-dihydro-1h-imidazol-2-yl)pyridine]manganese(ii) bis­(per­chlorate) acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970088/
https://www.ncbi.nlm.nih.gov/pubmed/21577391
http://dx.doi.org/10.1107/S1600536809029195
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