Cargando…
Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate
In the cation of the title compound, [Mn(C(11)H(13)N(5))(2)](ClO(4))(2)·CH(3)CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970088/ https://www.ncbi.nlm.nih.gov/pubmed/21577391 http://dx.doi.org/10.1107/S1600536809029195 |
_version_ | 1782190343216693248 |
---|---|
author | Shang, Shao-Ming Ren, Chun-Xia Wang, Xin Lu, Lu-De Yang, Xu-Jie |
author_facet | Shang, Shao-Ming Ren, Chun-Xia Wang, Xin Lu, Lu-De Yang, Xu-Jie |
author_sort | Shang, Shao-Ming |
collection | PubMed |
description | In the cation of the title compound, [Mn(C(11)H(13)N(5))(2)](ClO(4))(2)·CH(3)CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms of the perchlorate anions are disordered with occupancies in the ratio 0.593 (10):0.407 (10). In the crystal, molecules are stabilized by two N—H⋯O hydrogen bonds, forming zigzag chains along the a axis, which are further interconnected by N—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.50 (1) Å] into a three-dimensional network. |
format | Text |
id | pubmed-2970088 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29700882010-12-30 Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate Shang, Shao-Ming Ren, Chun-Xia Wang, Xin Lu, Lu-De Yang, Xu-Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Mn(C(11)H(13)N(5))(2)](ClO(4))(2)·CH(3)CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms of the perchlorate anions are disordered with occupancies in the ratio 0.593 (10):0.407 (10). In the crystal, molecules are stabilized by two N—H⋯O hydrogen bonds, forming zigzag chains along the a axis, which are further interconnected by N—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.50 (1) Å] into a three-dimensional network. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970088/ /pubmed/21577391 http://dx.doi.org/10.1107/S1600536809029195 Text en © Shang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shang, Shao-Ming Ren, Chun-Xia Wang, Xin Lu, Lu-De Yang, Xu-Jie Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate |
title | Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate |
title_full | Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate |
title_fullStr | Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate |
title_full_unstemmed | Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate |
title_short | Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate |
title_sort | bis[2,6-bis(4,5-dihydro-1h-imidazol-2-yl)pyridine]manganese(ii) bis(perchlorate) acetonitrile solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970088/ https://www.ncbi.nlm.nih.gov/pubmed/21577391 http://dx.doi.org/10.1107/S1600536809029195 |
work_keys_str_mv | AT shangshaoming bis26bis45dihydro1himidazol2ylpyridinemanganeseiibisperchlorateacetonitrilesolvate AT renchunxia bis26bis45dihydro1himidazol2ylpyridinemanganeseiibisperchlorateacetonitrilesolvate AT wangxin bis26bis45dihydro1himidazol2ylpyridinemanganeseiibisperchlorateacetonitrilesolvate AT lulude bis26bis45dihydro1himidazol2ylpyridinemanganeseiibisperchlorateacetonitrilesolvate AT yangxujie bis26bis45dihydro1himidazol2ylpyridinemanganeseiibisperchlorateacetonitrilesolvate |