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catena-Poly[copper(II)-di-μ-dicyan­amido-μ-1,3-di-4-pyridylpropane]

In the title compound, [Cu(C(2)N(3))(2)(C(13)H(14)N(2))](n), the Cu(II) atom, located on an inversion centre, adopts a distorted octa­hedral coordination by six N atoms, two from 1,3-di-4-pyridylpropane and four from dicyanamide ligands, with significantly different Cu—N distances. The metal centres...

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Detalles Bibliográficos
Autor principal: Zhang, Jinfang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970089/
https://www.ncbi.nlm.nih.gov/pubmed/21577406
http://dx.doi.org/10.1107/S1600536809030050
Descripción
Sumario:In the title compound, [Cu(C(2)N(3))(2)(C(13)H(14)N(2))](n), the Cu(II) atom, located on an inversion centre, adopts a distorted octa­hedral coordination by six N atoms, two from 1,3-di-4-pyridylpropane and four from dicyanamide ligands, with significantly different Cu—N distances. The metal centres are linked in an unusual triple-bridged mode into chains parallel to [101].