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catena-Poly[copper(II)-di-μ-dicyan­amido-μ-1,3-di-4-pyridylpropane]

In the title compound, [Cu(C(2)N(3))(2)(C(13)H(14)N(2))](n), the Cu(II) atom, located on an inversion centre, adopts a distorted octa­hedral coordination by six N atoms, two from 1,3-di-4-pyridylpropane and four from dicyanamide ligands, with significantly different Cu—N distances. The metal centres...

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Detalles Bibliográficos
Autor principal: Zhang, Jinfang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970089/
https://www.ncbi.nlm.nih.gov/pubmed/21577406
http://dx.doi.org/10.1107/S1600536809030050
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author Zhang, Jinfang
author_facet Zhang, Jinfang
author_sort Zhang, Jinfang
collection PubMed
description In the title compound, [Cu(C(2)N(3))(2)(C(13)H(14)N(2))](n), the Cu(II) atom, located on an inversion centre, adopts a distorted octa­hedral coordination by six N atoms, two from 1,3-di-4-pyridylpropane and four from dicyanamide ligands, with significantly different Cu—N distances. The metal centres are linked in an unusual triple-bridged mode into chains parallel to [101].
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spelling pubmed-29700892010-12-30 catena-Poly[copper(II)-di-μ-dicyan­amido-μ-1,3-di-4-pyridylpropane] Zhang, Jinfang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)N(3))(2)(C(13)H(14)N(2))](n), the Cu(II) atom, located on an inversion centre, adopts a distorted octa­hedral coordination by six N atoms, two from 1,3-di-4-pyridylpropane and four from dicyanamide ligands, with significantly different Cu—N distances. The metal centres are linked in an unusual triple-bridged mode into chains parallel to [101]. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970089/ /pubmed/21577406 http://dx.doi.org/10.1107/S1600536809030050 Text en © Jinfang Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Jinfang
catena-Poly[copper(II)-di-μ-dicyan­amido-μ-1,3-di-4-pyridylpropane]
title catena-Poly[copper(II)-di-μ-dicyan­amido-μ-1,3-di-4-pyridylpropane]
title_full catena-Poly[copper(II)-di-μ-dicyan­amido-μ-1,3-di-4-pyridylpropane]
title_fullStr catena-Poly[copper(II)-di-μ-dicyan­amido-μ-1,3-di-4-pyridylpropane]
title_full_unstemmed catena-Poly[copper(II)-di-μ-dicyan­amido-μ-1,3-di-4-pyridylpropane]
title_short catena-Poly[copper(II)-di-μ-dicyan­amido-μ-1,3-di-4-pyridylpropane]
title_sort catena-poly[copper(ii)-di-μ-dicyan­amido-μ-1,3-di-4-pyridylpropane]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970089/
https://www.ncbi.nlm.nih.gov/pubmed/21577406
http://dx.doi.org/10.1107/S1600536809030050
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