Cargando…
Diaquabis(N,N-diethylnicotinamide-κN (1))bis[4-(dimethylamino)benzoato-κO]cobalt(II)
The title Co(II) complex, [Co(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is centrosymmetric. It contains two dimethylaminobenzoate (DMAB) and two diethylnicotinamide (DENA) ligands and two water molecules, all of them being monodentate. The four O atoms in the equatorial plane around the...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970090/ https://www.ncbi.nlm.nih.gov/pubmed/21577412 http://dx.doi.org/10.1107/S1600536809030980 |
_version_ | 1782190343718961152 |
---|---|
author | Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_facet | Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_sort | Hökelek, Tuncer |
collection | PubMed |
description | The title Co(II) complex, [Co(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is centrosymmetric. It contains two dimethylaminobenzoate (DMAB) and two diethylnicotinamide (DENA) ligands and two water molecules, all of them being monodentate. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of DENA ligands with the Co—N distance of 2.1519 (11) Å in the axial positions. The Co atom is displaced out of the least-squares plane of the carboxylate group by −0.781 (1) Å. The dihedral angle between the carboxylate group and the adjacent benzene ring is 5.05 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 71.48 (5)°. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. Two weak C—H⋯π interactions are also present. |
format | Text |
id | pubmed-2970090 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29700902010-12-30 Diaquabis(N,N-diethylnicotinamide-κN (1))bis[4-(dimethylamino)benzoato-κO]cobalt(II) Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Co(II) complex, [Co(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is centrosymmetric. It contains two dimethylaminobenzoate (DMAB) and two diethylnicotinamide (DENA) ligands and two water molecules, all of them being monodentate. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of DENA ligands with the Co—N distance of 2.1519 (11) Å in the axial positions. The Co atom is displaced out of the least-squares plane of the carboxylate group by −0.781 (1) Å. The dihedral angle between the carboxylate group and the adjacent benzene ring is 5.05 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 71.48 (5)°. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. Two weak C—H⋯π interactions are also present. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970090/ /pubmed/21577412 http://dx.doi.org/10.1107/S1600536809030980 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Diaquabis(N,N-diethylnicotinamide-κN (1))bis[4-(dimethylamino)benzoato-κO]cobalt(II) |
title | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis[4-(dimethylamino)benzoato-κO]cobalt(II) |
title_full | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis[4-(dimethylamino)benzoato-κO]cobalt(II) |
title_fullStr | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis[4-(dimethylamino)benzoato-κO]cobalt(II) |
title_full_unstemmed | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis[4-(dimethylamino)benzoato-κO]cobalt(II) |
title_short | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis[4-(dimethylamino)benzoato-κO]cobalt(II) |
title_sort | diaquabis(n,n-diethylnicotinamide-κn
(1))bis[4-(dimethylamino)benzoato-κo]cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970090/ https://www.ncbi.nlm.nih.gov/pubmed/21577412 http://dx.doi.org/10.1107/S1600536809030980 |
work_keys_str_mv | AT hokelektuncer diaquabisnndiethylnicotinamidekn1bis4dimethylaminobenzoatokocobaltii AT dalhakan diaquabisnndiethylnicotinamidekn1bis4dimethylaminobenzoatokocobaltii AT tercanbarıs diaquabisnndiethylnicotinamidekn1bis4dimethylaminobenzoatokocobaltii AT aybirdiozgur diaquabisnndiethylnicotinamidekn1bis4dimethylaminobenzoatokocobaltii AT necefogluhacali diaquabisnndiethylnicotinamidekn1bis4dimethylaminobenzoatokocobaltii |