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Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis[4-(dimethyl­amino)­benzoato-κO]cobalt(II)

The title Co(II) complex, [Co(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is centrosymmetric. It contains two dimethyl­amino­benzoate (DMAB) and two diethyl­nicotinamide (DENA) ligands and two water mol­ecules, all of them being monodentate. The four O atoms in the equatorial plane around the...

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Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Aybirdi, Özgür, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970090/
https://www.ncbi.nlm.nih.gov/pubmed/21577412
http://dx.doi.org/10.1107/S1600536809030980
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author Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description The title Co(II) complex, [Co(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is centrosymmetric. It contains two dimethyl­amino­benzoate (DMAB) and two diethyl­nicotinamide (DENA) ligands and two water mol­ecules, all of them being monodentate. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of DENA ligands with the Co—N distance of 2.1519 (11) Å in the axial positions. The Co atom is displaced out of the least-squares plane of the carboxyl­ate group by −0.781 (1) Å. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 5.05 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 71.48 (5)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. Two weak C—H⋯π inter­actions are also present.
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spelling pubmed-29700902010-12-30 Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis[4-(dimethyl­amino)­benzoato-κO]cobalt(II) Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Co(II) complex, [Co(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is centrosymmetric. It contains two dimethyl­amino­benzoate (DMAB) and two diethyl­nicotinamide (DENA) ligands and two water mol­ecules, all of them being monodentate. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of DENA ligands with the Co—N distance of 2.1519 (11) Å in the axial positions. The Co atom is displaced out of the least-squares plane of the carboxyl­ate group by −0.781 (1) Å. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 5.05 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 71.48 (5)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. Two weak C—H⋯π inter­actions are also present. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970090/ /pubmed/21577412 http://dx.doi.org/10.1107/S1600536809030980 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis[4-(dimethyl­amino)­benzoato-κO]cobalt(II)
title Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis[4-(dimethyl­amino)­benzoato-κO]cobalt(II)
title_full Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis[4-(dimethyl­amino)­benzoato-κO]cobalt(II)
title_fullStr Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis[4-(dimethyl­amino)­benzoato-κO]cobalt(II)
title_full_unstemmed Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis[4-(dimethyl­amino)­benzoato-κO]cobalt(II)
title_short Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis[4-(dimethyl­amino)­benzoato-κO]cobalt(II)
title_sort diaqua­bis­(n,n-diethyl­nicotinamide-κn (1))bis[4-(dimethyl­amino)­benzoato-κo]cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970090/
https://www.ncbi.nlm.nih.gov/pubmed/21577412
http://dx.doi.org/10.1107/S1600536809030980
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