5-Bromo-2,3-dihydro-1H-cyclo­penta­[a]naphthalen-1-one

The title compound, C(13)H(9)BrO, has been synthesized by the intra­molecular Friedel–Crafts reaction of 1-(1-bromo-4-naphth­yl)-3-chloro­propan-1-one. There are two approximately planar [maximum deviations of 0.8 (2) and 0.4 (2) Å in the two mol­ecules] molecules in the asymmetric unit. The dihedra...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Liang, Sun, Di, Gao, Xiang-Zhi, Xie, Su-Yuan, Huang, Rong-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970092/
https://www.ncbi.nlm.nih.gov/pubmed/21577580
http://dx.doi.org/10.1107/S1600536809031547
_version_ 1782190344183480320
author Zhang, Liang
Sun, Di
Gao, Xiang-Zhi
Xie, Su-Yuan
Huang, Rong-Bin
author_facet Zhang, Liang
Sun, Di
Gao, Xiang-Zhi
Xie, Su-Yuan
Huang, Rong-Bin
author_sort Zhang, Liang
collection PubMed
description The title compound, C(13)H(9)BrO, has been synthesized by the intra­molecular Friedel–Crafts reaction of 1-(1-bromo-4-naphth­yl)-3-chloro­propan-1-one. There are two approximately planar [maximum deviations of 0.8 (2) and 0.4 (2) Å in the two mol­ecules] molecules in the asymmetric unit. The dihedral angle between their mean planes is 19.72 (8)°. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure.
format Text
id pubmed-2970092
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29700922010-12-30 5-Bromo-2,3-dihydro-1H-cyclo­penta­[a]naphthalen-1-one Zhang, Liang Sun, Di Gao, Xiang-Zhi Xie, Su-Yuan Huang, Rong-Bin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(9)BrO, has been synthesized by the intra­molecular Friedel–Crafts reaction of 1-(1-bromo-4-naphth­yl)-3-chloro­propan-1-one. There are two approximately planar [maximum deviations of 0.8 (2) and 0.4 (2) Å in the two mol­ecules] molecules in the asymmetric unit. The dihedral angle between their mean planes is 19.72 (8)°. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970092/ /pubmed/21577580 http://dx.doi.org/10.1107/S1600536809031547 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Liang
Sun, Di
Gao, Xiang-Zhi
Xie, Su-Yuan
Huang, Rong-Bin
5-Bromo-2,3-dihydro-1H-cyclo­penta­[a]naphthalen-1-one
title 5-Bromo-2,3-dihydro-1H-cyclo­penta­[a]naphthalen-1-one
title_full 5-Bromo-2,3-dihydro-1H-cyclo­penta­[a]naphthalen-1-one
title_fullStr 5-Bromo-2,3-dihydro-1H-cyclo­penta­[a]naphthalen-1-one
title_full_unstemmed 5-Bromo-2,3-dihydro-1H-cyclo­penta­[a]naphthalen-1-one
title_short 5-Bromo-2,3-dihydro-1H-cyclo­penta­[a]naphthalen-1-one
title_sort 5-bromo-2,3-dihydro-1h-cyclo­penta­[a]naphthalen-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970092/
https://www.ncbi.nlm.nih.gov/pubmed/21577580
http://dx.doi.org/10.1107/S1600536809031547
work_keys_str_mv AT zhangliang 5bromo23dihydro1hcyclopentaanaphthalen1one
AT sundi 5bromo23dihydro1hcyclopentaanaphthalen1one
AT gaoxiangzhi 5bromo23dihydro1hcyclopentaanaphthalen1one
AT xiesuyuan 5bromo23dihydro1hcyclopentaanaphthalen1one
AT huangrongbin 5bromo23dihydro1hcyclopentaanaphthalen1one

Ejemplares similares