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N′-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-4-hydroxy-3-methoxybenzohydrazide dihydrate
In the title compound, C(16)H(15)BrN(2)O(5)·2H(2)O, the dihedral angle between the two aromatic rings is 2.9 (2)° and an intramolecular O—H⋯N hydrogen bond is observed. One of the water molecule is disordered over two positions, with occupancies of 0.83 (3) and 0.17 (3). In the crystal structure,...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970095/ https://www.ncbi.nlm.nih.gov/pubmed/21577655 http://dx.doi.org/10.1107/S1600536809033522 |
Sumario: | In the title compound, C(16)H(15)BrN(2)O(5)·2H(2)O, the dihedral angle between the two aromatic rings is 2.9 (2)° and an intramolecular O—H⋯N hydrogen bond is observed. One of the water molecule is disordered over two positions, with occupancies of 0.83 (3) and 0.17 (3). In the crystal structure, molecules are linked into a three-dimensional network by intermolecular O—H⋯O, O—H⋯(O,O), O—H⋯N and N—H⋯O hydrogen bonds. π–π interactions involving Br-substituted benzene rings, with a centroid–centroid distance of 3.552 (3) Å are also observed. |
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