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N′-(5-Bromo-2-hydr­oxy-3-methoxy­benzyl­idene)-4-hydr­oxy-3-methoxy­benzohydrazide dihydrate

In the title compound, C(16)H(15)BrN(2)O(5)·2H(2)O, the dihedral angle between the two aromatic rings is 2.9 (2)° and an intra­molecular O—H⋯N hydrogen bond is observed. One of the water mol­ecule is disordered over two positions, with occupancies of 0.83 (3) and 0.17 (3). In the crystal structure,...

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Detalles Bibliográficos
Autores principales: Lu, Jiu-Fu, Min, Suo-Tian, Ge, Hong-Guang, Ji, Xiao-Hui, Bai, Yue-Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970095/
https://www.ncbi.nlm.nih.gov/pubmed/21577655
http://dx.doi.org/10.1107/S1600536809033522
Descripción
Sumario:In the title compound, C(16)H(15)BrN(2)O(5)·2H(2)O, the dihedral angle between the two aromatic rings is 2.9 (2)° and an intra­molecular O—H⋯N hydrogen bond is observed. One of the water mol­ecule is disordered over two positions, with occupancies of 0.83 (3) and 0.17 (3). In the crystal structure, mol­ecules are linked into a three-dimensional network by inter­molecular O—H⋯O, O—H⋯(O,O), O—H⋯N and N—H⋯O hydrogen bonds. π–π inter­actions involving Br-substituted benzene rings, with a centroid–centroid distance of 3.552 (3) Å are also observed.