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N′-(5-Bromo-2-hydr­oxy-3-methoxy­benzyl­idene)-4-hydr­oxy-3-methoxy­benzohydrazide dihydrate

In the title compound, C(16)H(15)BrN(2)O(5)·2H(2)O, the dihedral angle between the two aromatic rings is 2.9 (2)° and an intra­molecular O—H⋯N hydrogen bond is observed. One of the water mol­ecule is disordered over two positions, with occupancies of 0.83 (3) and 0.17 (3). In the crystal structure,...

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Autores principales: Lu, Jiu-Fu, Min, Suo-Tian, Ge, Hong-Guang, Ji, Xiao-Hui, Bai, Yue-Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970095/
https://www.ncbi.nlm.nih.gov/pubmed/21577655
http://dx.doi.org/10.1107/S1600536809033522
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author Lu, Jiu-Fu
Min, Suo-Tian
Ge, Hong-Guang
Ji, Xiao-Hui
Bai, Yue-Fei
author_facet Lu, Jiu-Fu
Min, Suo-Tian
Ge, Hong-Guang
Ji, Xiao-Hui
Bai, Yue-Fei
author_sort Lu, Jiu-Fu
collection PubMed
description In the title compound, C(16)H(15)BrN(2)O(5)·2H(2)O, the dihedral angle between the two aromatic rings is 2.9 (2)° and an intra­molecular O—H⋯N hydrogen bond is observed. One of the water mol­ecule is disordered over two positions, with occupancies of 0.83 (3) and 0.17 (3). In the crystal structure, mol­ecules are linked into a three-dimensional network by inter­molecular O—H⋯O, O—H⋯(O,O), O—H⋯N and N—H⋯O hydrogen bonds. π–π inter­actions involving Br-substituted benzene rings, with a centroid–centroid distance of 3.552 (3) Å are also observed.
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spelling pubmed-29700952010-12-30 N′-(5-Bromo-2-hydr­oxy-3-methoxy­benzyl­idene)-4-hydr­oxy-3-methoxy­benzohydrazide dihydrate Lu, Jiu-Fu Min, Suo-Tian Ge, Hong-Guang Ji, Xiao-Hui Bai, Yue-Fei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(15)BrN(2)O(5)·2H(2)O, the dihedral angle between the two aromatic rings is 2.9 (2)° and an intra­molecular O—H⋯N hydrogen bond is observed. One of the water mol­ecule is disordered over two positions, with occupancies of 0.83 (3) and 0.17 (3). In the crystal structure, mol­ecules are linked into a three-dimensional network by inter­molecular O—H⋯O, O—H⋯(O,O), O—H⋯N and N—H⋯O hydrogen bonds. π–π inter­actions involving Br-substituted benzene rings, with a centroid–centroid distance of 3.552 (3) Å are also observed. International Union of Crystallography 2009-08-29 /pmc/articles/PMC2970095/ /pubmed/21577655 http://dx.doi.org/10.1107/S1600536809033522 Text en © Lu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lu, Jiu-Fu
Min, Suo-Tian
Ge, Hong-Guang
Ji, Xiao-Hui
Bai, Yue-Fei
N′-(5-Bromo-2-hydr­oxy-3-methoxy­benzyl­idene)-4-hydr­oxy-3-methoxy­benzohydrazide dihydrate
title N′-(5-Bromo-2-hydr­oxy-3-methoxy­benzyl­idene)-4-hydr­oxy-3-methoxy­benzohydrazide dihydrate
title_full N′-(5-Bromo-2-hydr­oxy-3-methoxy­benzyl­idene)-4-hydr­oxy-3-methoxy­benzohydrazide dihydrate
title_fullStr N′-(5-Bromo-2-hydr­oxy-3-methoxy­benzyl­idene)-4-hydr­oxy-3-methoxy­benzohydrazide dihydrate
title_full_unstemmed N′-(5-Bromo-2-hydr­oxy-3-methoxy­benzyl­idene)-4-hydr­oxy-3-methoxy­benzohydrazide dihydrate
title_short N′-(5-Bromo-2-hydr­oxy-3-methoxy­benzyl­idene)-4-hydr­oxy-3-methoxy­benzohydrazide dihydrate
title_sort n′-(5-bromo-2-hydr­oxy-3-methoxy­benzyl­idene)-4-hydr­oxy-3-methoxy­benzohydrazide dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970095/
https://www.ncbi.nlm.nih.gov/pubmed/21577655
http://dx.doi.org/10.1107/S1600536809033522
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