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N′-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-4-hydroxy-3-methoxybenzohydrazide dihydrate
In the title compound, C(16)H(15)BrN(2)O(5)·2H(2)O, the dihedral angle between the two aromatic rings is 2.9 (2)° and an intramolecular O—H⋯N hydrogen bond is observed. One of the water molecule is disordered over two positions, with occupancies of 0.83 (3) and 0.17 (3). In the crystal structure,...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970095/ https://www.ncbi.nlm.nih.gov/pubmed/21577655 http://dx.doi.org/10.1107/S1600536809033522 |
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author | Lu, Jiu-Fu Min, Suo-Tian Ge, Hong-Guang Ji, Xiao-Hui Bai, Yue-Fei |
author_facet | Lu, Jiu-Fu Min, Suo-Tian Ge, Hong-Guang Ji, Xiao-Hui Bai, Yue-Fei |
author_sort | Lu, Jiu-Fu |
collection | PubMed |
description | In the title compound, C(16)H(15)BrN(2)O(5)·2H(2)O, the dihedral angle between the two aromatic rings is 2.9 (2)° and an intramolecular O—H⋯N hydrogen bond is observed. One of the water molecule is disordered over two positions, with occupancies of 0.83 (3) and 0.17 (3). In the crystal structure, molecules are linked into a three-dimensional network by intermolecular O—H⋯O, O—H⋯(O,O), O—H⋯N and N—H⋯O hydrogen bonds. π–π interactions involving Br-substituted benzene rings, with a centroid–centroid distance of 3.552 (3) Å are also observed. |
format | Text |
id | pubmed-2970095 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29700952010-12-30 N′-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-4-hydroxy-3-methoxybenzohydrazide dihydrate Lu, Jiu-Fu Min, Suo-Tian Ge, Hong-Guang Ji, Xiao-Hui Bai, Yue-Fei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(15)BrN(2)O(5)·2H(2)O, the dihedral angle between the two aromatic rings is 2.9 (2)° and an intramolecular O—H⋯N hydrogen bond is observed. One of the water molecule is disordered over two positions, with occupancies of 0.83 (3) and 0.17 (3). In the crystal structure, molecules are linked into a three-dimensional network by intermolecular O—H⋯O, O—H⋯(O,O), O—H⋯N and N—H⋯O hydrogen bonds. π–π interactions involving Br-substituted benzene rings, with a centroid–centroid distance of 3.552 (3) Å are also observed. International Union of Crystallography 2009-08-29 /pmc/articles/PMC2970095/ /pubmed/21577655 http://dx.doi.org/10.1107/S1600536809033522 Text en © Lu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Lu, Jiu-Fu Min, Suo-Tian Ge, Hong-Guang Ji, Xiao-Hui Bai, Yue-Fei N′-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-4-hydroxy-3-methoxybenzohydrazide dihydrate |
title |
N′-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-4-hydroxy-3-methoxybenzohydrazide dihydrate |
title_full |
N′-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-4-hydroxy-3-methoxybenzohydrazide dihydrate |
title_fullStr |
N′-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-4-hydroxy-3-methoxybenzohydrazide dihydrate |
title_full_unstemmed |
N′-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-4-hydroxy-3-methoxybenzohydrazide dihydrate |
title_short |
N′-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-4-hydroxy-3-methoxybenzohydrazide dihydrate |
title_sort | n′-(5-bromo-2-hydroxy-3-methoxybenzylidene)-4-hydroxy-3-methoxybenzohydrazide dihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970095/ https://www.ncbi.nlm.nih.gov/pubmed/21577655 http://dx.doi.org/10.1107/S1600536809033522 |
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