2,2,3,3,5,5,6,6-Octa-p-tolyl-1,4-dioxa-2,3,5,6-tetra­germacyclo­hexane dichloro­methane disolvate

The title compound, C(56)H(56)Ge(4)O(2)·2CH(2)Cl(2) or Tol(8)Ge(4)O(2)·2CH(2)Cl(2) (Tol = p-CH(3)C(6)H(4)), was obtained serendipitously during the attempted synthesis of a branched oligogermane from Tol(3)GeNMe(2) and PhGeH(3). The mol­ecule contains an inversion center in the middle of the Ge(4)O(...

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Autores principales: Amadoruge, Monika L., Rheingold, Arnold L., Weinert, Charles S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970098/
https://www.ncbi.nlm.nih.gov/pubmed/21577590
http://dx.doi.org/10.1107/S1600536809032012
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author Amadoruge, Monika L.
Rheingold, Arnold L.
Weinert, Charles S.
author_facet Amadoruge, Monika L.
Rheingold, Arnold L.
Weinert, Charles S.
author_sort Amadoruge, Monika L.
collection PubMed
description The title compound, C(56)H(56)Ge(4)O(2)·2CH(2)Cl(2) or Tol(8)Ge(4)O(2)·2CH(2)Cl(2) (Tol = p-CH(3)C(6)H(4)), was obtained serendipitously during the attempted synthesis of a branched oligogermane from Tol(3)GeNMe(2) and PhGeH(3). The mol­ecule contains an inversion center in the middle of the Ge(4)O(2) ring which is in a chair conformation. The Ge—Ge bond distance is 2.4418 (5) Å and the Ge—O bond distances are 1.790 (2) and 1.785 (2) Å. The torsion angles within the Ge(4)O(2) ring are −56.7 (1) and 56.1 (1)° for the Ge—Ge—O—Ge angles and −43.9 (1)° for the O—Ge—Ge—O angle.
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spelling pubmed-29700982010-12-30 2,2,3,3,5,5,6,6-Octa-p-tolyl-1,4-dioxa-2,3,5,6-tetra­germacyclo­hexane dichloro­methane disolvate Amadoruge, Monika L. Rheingold, Arnold L. Weinert, Charles S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(56)H(56)Ge(4)O(2)·2CH(2)Cl(2) or Tol(8)Ge(4)O(2)·2CH(2)Cl(2) (Tol = p-CH(3)C(6)H(4)), was obtained serendipitously during the attempted synthesis of a branched oligogermane from Tol(3)GeNMe(2) and PhGeH(3). The mol­ecule contains an inversion center in the middle of the Ge(4)O(2) ring which is in a chair conformation. The Ge—Ge bond distance is 2.4418 (5) Å and the Ge—O bond distances are 1.790 (2) and 1.785 (2) Å. The torsion angles within the Ge(4)O(2) ring are −56.7 (1) and 56.1 (1)° for the Ge—Ge—O—Ge angles and −43.9 (1)° for the O—Ge—Ge—O angle. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970098/ /pubmed/21577590 http://dx.doi.org/10.1107/S1600536809032012 Text en © Amadoruge et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Amadoruge, Monika L.
Rheingold, Arnold L.
Weinert, Charles S.
2,2,3,3,5,5,6,6-Octa-p-tolyl-1,4-dioxa-2,3,5,6-tetra­germacyclo­hexane dichloro­methane disolvate
title 2,2,3,3,5,5,6,6-Octa-p-tolyl-1,4-dioxa-2,3,5,6-tetra­germacyclo­hexane dichloro­methane disolvate
title_full 2,2,3,3,5,5,6,6-Octa-p-tolyl-1,4-dioxa-2,3,5,6-tetra­germacyclo­hexane dichloro­methane disolvate
title_fullStr 2,2,3,3,5,5,6,6-Octa-p-tolyl-1,4-dioxa-2,3,5,6-tetra­germacyclo­hexane dichloro­methane disolvate
title_full_unstemmed 2,2,3,3,5,5,6,6-Octa-p-tolyl-1,4-dioxa-2,3,5,6-tetra­germacyclo­hexane dichloro­methane disolvate
title_short 2,2,3,3,5,5,6,6-Octa-p-tolyl-1,4-dioxa-2,3,5,6-tetra­germacyclo­hexane dichloro­methane disolvate
title_sort 2,2,3,3,5,5,6,6-octa-p-tolyl-1,4-dioxa-2,3,5,6-tetra­germacyclo­hexane dichloro­methane disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970098/
https://www.ncbi.nlm.nih.gov/pubmed/21577590
http://dx.doi.org/10.1107/S1600536809032012
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