Bis[4-chloro-2-(imino­meth­yl)phenolato]copper(II) methanol disolvate

The title compound, [Cu(C(7)H(5)ClNO)(2)]·2CH(3)OH, possesses crystallographic twofold symmetry, with the twofold axis passing through the central Cu(II) ion. The metal centre is coordinated by two O atoms and two N atoms from two symmetry-related Schiff base ligands, forming a slightly distorted ci...

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Detalles Bibliográficos
Autor principal: Qin, Bei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970101/
https://www.ncbi.nlm.nih.gov/pubmed/21577448
http://dx.doi.org/10.1107/S1600536809031043
Descripción
Sumario:The title compound, [Cu(C(7)H(5)ClNO)(2)]·2CH(3)OH, possesses crystallographic twofold symmetry, with the twofold axis passing through the central Cu(II) ion. The metal centre is coordinated by two O atoms and two N atoms from two symmetry-related Schiff base ligands, forming a slightly distorted cis-CuN(2)O(2) square-planar geometry. The complex mol­ecules are linked via the solvent methanol mol­ecules by O—H⋯O and N—H⋯O hydrogen bonds, leading to the formation of chains along the b axis.

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