Bis[4-chloro-2-(imino­meth­yl)phenolato]copper(II) methanol disolvate

The title compound, [Cu(C(7)H(5)ClNO)(2)]·2CH(3)OH, possesses crystallographic twofold symmetry, with the twofold axis passing through the central Cu(II) ion. The metal centre is coordinated by two O atoms and two N atoms from two symmetry-related Schiff base ligands, forming a slightly distorted ci...

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Detalles Bibliográficos
Autor principal: Qin, Bei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970101/
https://www.ncbi.nlm.nih.gov/pubmed/21577448
http://dx.doi.org/10.1107/S1600536809031043
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author Qin, Bei
author_facet Qin, Bei
author_sort Qin, Bei
collection PubMed
description The title compound, [Cu(C(7)H(5)ClNO)(2)]·2CH(3)OH, possesses crystallographic twofold symmetry, with the twofold axis passing through the central Cu(II) ion. The metal centre is coordinated by two O atoms and two N atoms from two symmetry-related Schiff base ligands, forming a slightly distorted cis-CuN(2)O(2) square-planar geometry. The complex mol­ecules are linked via the solvent methanol mol­ecules by O—H⋯O and N—H⋯O hydrogen bonds, leading to the formation of chains along the b axis.
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spelling pubmed-29701012010-12-30 Bis[4-chloro-2-(imino­meth­yl)phenolato]copper(II) methanol disolvate Qin, Bei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(7)H(5)ClNO)(2)]·2CH(3)OH, possesses crystallographic twofold symmetry, with the twofold axis passing through the central Cu(II) ion. The metal centre is coordinated by two O atoms and two N atoms from two symmetry-related Schiff base ligands, forming a slightly distorted cis-CuN(2)O(2) square-planar geometry. The complex mol­ecules are linked via the solvent methanol mol­ecules by O—H⋯O and N—H⋯O hydrogen bonds, leading to the formation of chains along the b axis. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970101/ /pubmed/21577448 http://dx.doi.org/10.1107/S1600536809031043 Text en © Bei Qin 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Qin, Bei
Bis[4-chloro-2-(imino­meth­yl)phenolato]copper(II) methanol disolvate
title Bis[4-chloro-2-(imino­meth­yl)phenolato]copper(II) methanol disolvate
title_full Bis[4-chloro-2-(imino­meth­yl)phenolato]copper(II) methanol disolvate
title_fullStr Bis[4-chloro-2-(imino­meth­yl)phenolato]copper(II) methanol disolvate
title_full_unstemmed Bis[4-chloro-2-(imino­meth­yl)phenolato]copper(II) methanol disolvate
title_short Bis[4-chloro-2-(imino­meth­yl)phenolato]copper(II) methanol disolvate
title_sort bis[4-chloro-2-(imino­meth­yl)phenolato]copper(ii) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970101/
https://www.ncbi.nlm.nih.gov/pubmed/21577448
http://dx.doi.org/10.1107/S1600536809031043
work_keys_str_mv AT qinbei bis4chloro2iminomethylphenolatocopperiimethanoldisolvate

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