Octa­kis[2,2′,5,5′-tetra­thia­fulvalenium(0.5+)] bis­[hexa­molybdate(2−)] acetonitrile solvate

The asymmetric unit of the title compound, (C(6)H(4)S(4))(8)[Mo(6)O(19)](2)·CH(3)CN, contains two halves of two centrosymmetric [Mo(6)O(19)](2−) hexa­molybdate anions, which are each built up from six distorted MoO(6) octa­hedra sharing common edges and one common vertex at the central O atom, six t...

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Detalles Bibliográficos
Autores principales: Zebiri, Ikram, Anak, Berkahoum, Djebli, Yacine, Boufas, Sihem, Bencharif, Leïla
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970104/
https://www.ncbi.nlm.nih.gov/pubmed/21577422
http://dx.doi.org/10.1107/S1600536809031092
Descripción
Sumario:The asymmetric unit of the title compound, (C(6)H(4)S(4))(8)[Mo(6)O(19)](2)·CH(3)CN, contains two halves of two centrosymmetric [Mo(6)O(19)](2−) hexa­molybdate anions, which are each built up from six distorted MoO(6) octa­hedra sharing common edges and one common vertex at the central O atom, six tetra­thia­fulvalene cations (three of which are located on mirror planes) to balance the charge and a half of an acetonitrile solvent mol­ecule, likewise located on a mirror plane. The two central hexa­molybdate O atoms occupy special positions 2a and 2d, respectively. The cations and anions are inter­linked through C—H⋯O contacts.

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