Octa­kis[2,2′,5,5′-tetra­thia­fulvalenium(0.5+)] bis­[hexa­molybdate(2−)] acetonitrile solvate

The asymmetric unit of the title compound, (C(6)H(4)S(4))(8)[Mo(6)O(19)](2)·CH(3)CN, contains two halves of two centrosymmetric [Mo(6)O(19)](2−) hexa­molybdate anions, which are each built up from six distorted MoO(6) octa­hedra sharing common edges and one common vertex at the central O atom, six t...

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Autores principales: Zebiri, Ikram, Anak, Berkahoum, Djebli, Yacine, Boufas, Sihem, Bencharif, Leïla
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970104/
https://www.ncbi.nlm.nih.gov/pubmed/21577422
http://dx.doi.org/10.1107/S1600536809031092
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author Zebiri, Ikram
Anak, Berkahoum
Djebli, Yacine
Boufas, Sihem
Bencharif, Leïla
author_facet Zebiri, Ikram
Anak, Berkahoum
Djebli, Yacine
Boufas, Sihem
Bencharif, Leïla
author_sort Zebiri, Ikram
collection PubMed
description The asymmetric unit of the title compound, (C(6)H(4)S(4))(8)[Mo(6)O(19)](2)·CH(3)CN, contains two halves of two centrosymmetric [Mo(6)O(19)](2−) hexa­molybdate anions, which are each built up from six distorted MoO(6) octa­hedra sharing common edges and one common vertex at the central O atom, six tetra­thia­fulvalene cations (three of which are located on mirror planes) to balance the charge and a half of an acetonitrile solvent mol­ecule, likewise located on a mirror plane. The two central hexa­molybdate O atoms occupy special positions 2a and 2d, respectively. The cations and anions are inter­linked through C—H⋯O contacts.
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spelling pubmed-29701042010-12-30 Octa­kis[2,2′,5,5′-tetra­thia­fulvalenium(0.5+)] bis­[hexa­molybdate(2−)] acetonitrile solvate Zebiri, Ikram Anak, Berkahoum Djebli, Yacine Boufas, Sihem Bencharif, Leïla Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(6)H(4)S(4))(8)[Mo(6)O(19)](2)·CH(3)CN, contains two halves of two centrosymmetric [Mo(6)O(19)](2−) hexa­molybdate anions, which are each built up from six distorted MoO(6) octa­hedra sharing common edges and one common vertex at the central O atom, six tetra­thia­fulvalene cations (three of which are located on mirror planes) to balance the charge and a half of an acetonitrile solvent mol­ecule, likewise located on a mirror plane. The two central hexa­molybdate O atoms occupy special positions 2a and 2d, respectively. The cations and anions are inter­linked through C—H⋯O contacts. International Union of Crystallography 2009-08-12 /pmc/articles/PMC2970104/ /pubmed/21577422 http://dx.doi.org/10.1107/S1600536809031092 Text en © Zebiri et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zebiri, Ikram
Anak, Berkahoum
Djebli, Yacine
Boufas, Sihem
Bencharif, Leïla
Octa­kis[2,2′,5,5′-tetra­thia­fulvalenium(0.5+)] bis­[hexa­molybdate(2−)] acetonitrile solvate
title Octa­kis[2,2′,5,5′-tetra­thia­fulvalenium(0.5+)] bis­[hexa­molybdate(2−)] acetonitrile solvate
title_full Octa­kis[2,2′,5,5′-tetra­thia­fulvalenium(0.5+)] bis­[hexa­molybdate(2−)] acetonitrile solvate
title_fullStr Octa­kis[2,2′,5,5′-tetra­thia­fulvalenium(0.5+)] bis­[hexa­molybdate(2−)] acetonitrile solvate
title_full_unstemmed Octa­kis[2,2′,5,5′-tetra­thia­fulvalenium(0.5+)] bis­[hexa­molybdate(2−)] acetonitrile solvate
title_short Octa­kis[2,2′,5,5′-tetra­thia­fulvalenium(0.5+)] bis­[hexa­molybdate(2−)] acetonitrile solvate
title_sort octa­kis[2,2′,5,5′-tetra­thia­fulvalenium(0.5+)] bis­[hexa­molybdate(2−)] acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970104/
https://www.ncbi.nlm.nih.gov/pubmed/21577422
http://dx.doi.org/10.1107/S1600536809031092
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AT anakberkahoum octakis2255tetrathiafulvalenium05bishexamolybdate2acetonitrilesolvate
AT djebliyacine octakis2255tetrathiafulvalenium05bishexamolybdate2acetonitrilesolvate
AT boufassihem octakis2255tetrathiafulvalenium05bishexamolybdate2acetonitrilesolvate
AT bencharifleila octakis2255tetrathiafulvalenium05bishexamolybdate2acetonitrilesolvate

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