(Z)-2,2,2-Trichloro-N (2)-cyano­acetamidine

The title compound, C(3)H(2)Cl(3)N(3), crystallizes as the Z isomer with respect to the C=N bond. The –C(NH(2))=NCN functional group is effectively planar (r.m.s. deviation = 0.016 Å), with only the three Cl atoms out of the mol­ecular plane. A strong network of N—H⋯N hydrogen bonds forms dimers whi...

Descripción completa

Detalles Bibliográficos
Autores principales: Baker, A. Elizabeth, Boeré, René T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970111/
https://www.ncbi.nlm.nih.gov/pubmed/21577545
http://dx.doi.org/10.1107/S1600536809031079
_version_ 1782190349803847680
author Baker, A. Elizabeth
Boeré, René T.
author_facet Baker, A. Elizabeth
Boeré, René T.
author_sort Baker, A. Elizabeth
collection PubMed
description The title compound, C(3)H(2)Cl(3)N(3), crystallizes as the Z isomer with respect to the C=N bond. The –C(NH(2))=NCN functional group is effectively planar (r.m.s. deviation = 0.016 Å), with only the three Cl atoms out of the mol­ecular plane. A strong network of N—H⋯N hydrogen bonds forms dimers which are associated into ribbons in the crystal structure. Hydrogen bonding is suspected to be the cause of the near-equivalence of the formal C—N and C=N bonds (Δ(CN) = 0.008 Å)
format Text
id pubmed-2970111
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29701112010-12-30 (Z)-2,2,2-Trichloro-N (2)-cyano­acetamidine Baker, A. Elizabeth Boeré, René T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(3)H(2)Cl(3)N(3), crystallizes as the Z isomer with respect to the C=N bond. The –C(NH(2))=NCN functional group is effectively planar (r.m.s. deviation = 0.016 Å), with only the three Cl atoms out of the mol­ecular plane. A strong network of N—H⋯N hydrogen bonds forms dimers which are associated into ribbons in the crystal structure. Hydrogen bonding is suspected to be the cause of the near-equivalence of the formal C—N and C=N bonds (Δ(CN) = 0.008 Å) International Union of Crystallography 2009-08-12 /pmc/articles/PMC2970111/ /pubmed/21577545 http://dx.doi.org/10.1107/S1600536809031079 Text en © Baker and Boeré 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Baker, A. Elizabeth
Boeré, René T.
(Z)-2,2,2-Trichloro-N (2)-cyano­acetamidine
title (Z)-2,2,2-Trichloro-N (2)-cyano­acetamidine
title_full (Z)-2,2,2-Trichloro-N (2)-cyano­acetamidine
title_fullStr (Z)-2,2,2-Trichloro-N (2)-cyano­acetamidine
title_full_unstemmed (Z)-2,2,2-Trichloro-N (2)-cyano­acetamidine
title_short (Z)-2,2,2-Trichloro-N (2)-cyano­acetamidine
title_sort (z)-2,2,2-trichloro-n (2)-cyano­acetamidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970111/
https://www.ncbi.nlm.nih.gov/pubmed/21577545
http://dx.doi.org/10.1107/S1600536809031079
work_keys_str_mv AT bakeraelizabeth z222trichloron2cyanoacetamidine
AT boererenet z222trichloron2cyanoacetamidine

Ejemplares similares