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dl-Asparaginium nitrate

In the title compound, C(4)H(9)N(2)O(3) (+)·NO(3) (−), alternatively called (1RS)-2-carbamoyl-1-carboxy­ethanaminium nitrate, the asymmetric unit comprises one asparaginium cation and one nitrate anion. The strongest cation–cation O—H⋯O hydrogen bond in the structure, together with other strong cati...

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Detalles Bibliográficos
Autores principales: Moussa Slimane, Nabila, Cherouana, Aouatef, Bendjeddou, Lamia, Dahaoui, Slimane, Lecomte, Claude
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970112/
https://www.ncbi.nlm.nih.gov/pubmed/21577586
http://dx.doi.org/10.1107/S1600536809031730
Descripción
Sumario:In the title compound, C(4)H(9)N(2)O(3) (+)·NO(3) (−), alternatively called (1RS)-2-carbamoyl-1-carboxy­ethanaminium nitrate, the asymmetric unit comprises one asparaginium cation and one nitrate anion. The strongest cation–cation O—H⋯O hydrogen bond in the structure, together with other strong cation–cation N—H⋯O hydrogen bonds, generates a succession of infinite chains of R (2) (2)(8) rings along the b axis. Additional cation–cation C—H⋯O hydrogen bonds link these chains into two-dimensional layers formed by alternating R (4) (4)(24) and R (4) (2)(12) rings. Connections between these layers are provided by the strong cation–anion N—H⋯O hydrogen bonds, as well as by one weak C—H⋯O inter­action, thus forming a three-dimensional network. Some of the cation–anion N—H⋯O hydrogen bonds are bifurcated of the type D—H⋯(A (1),A (2)).