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dl-Asparaginium nitrate

In the title compound, C(4)H(9)N(2)O(3) (+)·NO(3) (−), alternatively called (1RS)-2-carbamoyl-1-carboxy­ethanaminium nitrate, the asymmetric unit comprises one asparaginium cation and one nitrate anion. The strongest cation–cation O—H⋯O hydrogen bond in the structure, together with other strong cati...

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Autores principales: Moussa Slimane, Nabila, Cherouana, Aouatef, Bendjeddou, Lamia, Dahaoui, Slimane, Lecomte, Claude
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970112/
https://www.ncbi.nlm.nih.gov/pubmed/21577586
http://dx.doi.org/10.1107/S1600536809031730
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author Moussa Slimane, Nabila
Cherouana, Aouatef
Bendjeddou, Lamia
Dahaoui, Slimane
Lecomte, Claude
author_facet Moussa Slimane, Nabila
Cherouana, Aouatef
Bendjeddou, Lamia
Dahaoui, Slimane
Lecomte, Claude
author_sort Moussa Slimane, Nabila
collection PubMed
description In the title compound, C(4)H(9)N(2)O(3) (+)·NO(3) (−), alternatively called (1RS)-2-carbamoyl-1-carboxy­ethanaminium nitrate, the asymmetric unit comprises one asparaginium cation and one nitrate anion. The strongest cation–cation O—H⋯O hydrogen bond in the structure, together with other strong cation–cation N—H⋯O hydrogen bonds, generates a succession of infinite chains of R (2) (2)(8) rings along the b axis. Additional cation–cation C—H⋯O hydrogen bonds link these chains into two-dimensional layers formed by alternating R (4) (4)(24) and R (4) (2)(12) rings. Connections between these layers are provided by the strong cation–anion N—H⋯O hydrogen bonds, as well as by one weak C—H⋯O inter­action, thus forming a three-dimensional network. Some of the cation–anion N—H⋯O hydrogen bonds are bifurcated of the type D—H⋯(A (1),A (2)).
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spelling pubmed-29701122010-12-30 dl-Asparaginium nitrate Moussa Slimane, Nabila Cherouana, Aouatef Bendjeddou, Lamia Dahaoui, Slimane Lecomte, Claude Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(4)H(9)N(2)O(3) (+)·NO(3) (−), alternatively called (1RS)-2-carbamoyl-1-carboxy­ethanaminium nitrate, the asymmetric unit comprises one asparaginium cation and one nitrate anion. The strongest cation–cation O—H⋯O hydrogen bond in the structure, together with other strong cation–cation N—H⋯O hydrogen bonds, generates a succession of infinite chains of R (2) (2)(8) rings along the b axis. Additional cation–cation C—H⋯O hydrogen bonds link these chains into two-dimensional layers formed by alternating R (4) (4)(24) and R (4) (2)(12) rings. Connections between these layers are provided by the strong cation–anion N—H⋯O hydrogen bonds, as well as by one weak C—H⋯O inter­action, thus forming a three-dimensional network. Some of the cation–anion N—H⋯O hydrogen bonds are bifurcated of the type D—H⋯(A (1),A (2)). International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970112/ /pubmed/21577586 http://dx.doi.org/10.1107/S1600536809031730 Text en © Moussa Slimane et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moussa Slimane, Nabila
Cherouana, Aouatef
Bendjeddou, Lamia
Dahaoui, Slimane
Lecomte, Claude
dl-Asparaginium nitrate
title dl-Asparaginium nitrate
title_full dl-Asparaginium nitrate
title_fullStr dl-Asparaginium nitrate
title_full_unstemmed dl-Asparaginium nitrate
title_short dl-Asparaginium nitrate
title_sort dl-asparaginium nitrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970112/
https://www.ncbi.nlm.nih.gov/pubmed/21577586
http://dx.doi.org/10.1107/S1600536809031730
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