Bis{2-[2-(dimethyl­amino)ethyl­imino­meth­yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate

In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N′-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa­hedral geometry for the metal ion. In the crystal, the water mol­ecule (O-atom site symm...

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Detalles Bibliográficos
Autores principales: Cai, Ying-Jie, Li, Jin, Huang, Peng, Zeng, Qing-Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970116/
https://www.ncbi.nlm.nih.gov/pubmed/21577479
http://dx.doi.org/10.1107/S1600536809033650
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author Cai, Ying-Jie
Li, Jin
Huang, Peng
Zeng, Qing-Fu
author_facet Cai, Ying-Jie
Li, Jin
Huang, Peng
Zeng, Qing-Fu
author_sort Cai, Ying-Jie
collection PubMed
description In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N′-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa­hedral geometry for the metal ion. In the crystal, the water mol­ecule (O-atom site symmetry 2) inter­acts with nearby complex mol­ecules by way of bifurcated O—H⋯(O,S) hydrogen bonds.
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spelling pubmed-29701162010-12-30 Bis{2-[2-(dimethyl­amino)ethyl­imino­meth­yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate Cai, Ying-Jie Li, Jin Huang, Peng Zeng, Qing-Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N′-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa­hedral geometry for the metal ion. In the crystal, the water mol­ecule (O-atom site symmetry 2) inter­acts with nearby complex mol­ecules by way of bifurcated O—H⋯(O,S) hydrogen bonds. International Union of Crystallography 2009-08-29 /pmc/articles/PMC2970116/ /pubmed/21577479 http://dx.doi.org/10.1107/S1600536809033650 Text en © Cai et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Ying-Jie
Li, Jin
Huang, Peng
Zeng, Qing-Fu
Bis{2-[2-(dimethyl­amino)ethyl­imino­meth­yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate
title Bis{2-[2-(dimethyl­amino)ethyl­imino­meth­yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate
title_full Bis{2-[2-(dimethyl­amino)ethyl­imino­meth­yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate
title_fullStr Bis{2-[2-(dimethyl­amino)ethyl­imino­meth­yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate
title_full_unstemmed Bis{2-[2-(dimethyl­amino)ethyl­imino­meth­yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate
title_short Bis{2-[2-(dimethyl­amino)ethyl­imino­meth­yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate
title_sort bis{2-[2-(dimethyl­amino)ethyl­imino­meth­yl]-4,6-disulfanylphenolato}cobalt(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970116/
https://www.ncbi.nlm.nih.gov/pubmed/21577479
http://dx.doi.org/10.1107/S1600536809033650
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AT zengqingfu bis22dimethylaminoethyliminomethyl46disulfanylphenolatocobaltiimonohydrate

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