N-Cyano-7α-methoxy­carbonyl-6,14-endo-ethenotetra­hydro­northebaine

In the title compound (systematic name: methyl 17-cyano-3,6-dimeth­oxy-4,5α-ep­oxy-6,14-endo-ethenomorphinan-7-carboxyl­ate), C(23)H(24)N(2)O(5), the dihydro­furan ring adopts a twist conformation, while the piperidine ring is in a chair conformation. The benzene-fused cyclo­hexene ring adopts an en...

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Autores principales: Odabaşoğlu, Mustafa, Yavuz, Serkan, Pamir, Özgür, Büyükgüngör, Orhan, Yıldırır, Yılmaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970118/
https://www.ncbi.nlm.nih.gov/pubmed/21577607
http://dx.doi.org/10.1107/S1600536809032450
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author Odabaşoğlu, Mustafa
Yavuz, Serkan
Pamir, Özgür
Büyükgüngör, Orhan
Yıldırır, Yılmaz
author_facet Odabaşoğlu, Mustafa
Yavuz, Serkan
Pamir, Özgür
Büyükgüngör, Orhan
Yıldırır, Yılmaz
author_sort Odabaşoğlu, Mustafa
collection PubMed
description In the title compound (systematic name: methyl 17-cyano-3,6-dimeth­oxy-4,5α-ep­oxy-6,14-endo-ethenomorphinan-7-carboxyl­ate), C(23)H(24)N(2)O(5), the dihydro­furan ring adopts a twist conformation, while the piperidine ring is in a chair conformation. The benzene-fused cyclo­hexene ring adopts an envelope conformation. An intra­molecular C—H⋯O hydrogen bond is observed. Inter­molecular C—H⋯N and C—H⋯O hydrogen bonds form C(5) chains along the a and b axes, respectively, and together they form a three-dimensional network.
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spelling pubmed-29701182010-12-30 N-Cyano-7α-methoxy­carbonyl-6,14-endo-ethenotetra­hydro­northebaine Odabaşoğlu, Mustafa Yavuz, Serkan Pamir, Özgür Büyükgüngör, Orhan Yıldırır, Yılmaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound (systematic name: methyl 17-cyano-3,6-dimeth­oxy-4,5α-ep­oxy-6,14-endo-ethenomorphinan-7-carboxyl­ate), C(23)H(24)N(2)O(5), the dihydro­furan ring adopts a twist conformation, while the piperidine ring is in a chair conformation. The benzene-fused cyclo­hexene ring adopts an envelope conformation. An intra­molecular C—H⋯O hydrogen bond is observed. Inter­molecular C—H⋯N and C—H⋯O hydrogen bonds form C(5) chains along the a and b axes, respectively, and together they form a three-dimensional network. International Union of Crystallography 2009-08-22 /pmc/articles/PMC2970118/ /pubmed/21577607 http://dx.doi.org/10.1107/S1600536809032450 Text en © Odabaşoğlu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Odabaşoğlu, Mustafa
Yavuz, Serkan
Pamir, Özgür
Büyükgüngör, Orhan
Yıldırır, Yılmaz
N-Cyano-7α-methoxy­carbonyl-6,14-endo-ethenotetra­hydro­northebaine
title N-Cyano-7α-methoxy­carbonyl-6,14-endo-ethenotetra­hydro­northebaine
title_full N-Cyano-7α-methoxy­carbonyl-6,14-endo-ethenotetra­hydro­northebaine
title_fullStr N-Cyano-7α-methoxy­carbonyl-6,14-endo-ethenotetra­hydro­northebaine
title_full_unstemmed N-Cyano-7α-methoxy­carbonyl-6,14-endo-ethenotetra­hydro­northebaine
title_short N-Cyano-7α-methoxy­carbonyl-6,14-endo-ethenotetra­hydro­northebaine
title_sort n-cyano-7α-methoxy­carbonyl-6,14-endo-ethenotetra­hydro­northebaine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970118/
https://www.ncbi.nlm.nih.gov/pubmed/21577607
http://dx.doi.org/10.1107/S1600536809032450
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AT yavuzserkan ncyano7amethoxycarbonyl614endoethenotetrahydronorthebaine
AT pamirozgur ncyano7amethoxycarbonyl614endoethenotetrahydronorthebaine
AT buyukgungororhan ncyano7amethoxycarbonyl614endoethenotetrahydronorthebaine
AT yıldırıryılmaz ncyano7amethoxycarbonyl614endoethenotetrahydronorthebaine

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