tert-Butyl N-[1-diazo­acetyl-3-(methyl­sulfan­yl)prop­yl]carbamate

In the enanti­omerically pure title compound, C(11)H(19)N(3)O(3)S, the chain C—N—C(O)—O—C—C (from the asymmetric carbon to a methyl of the tert-butyl group) displays an extended conformation. In the crystal, mol­ecules are linked into chains parallel to the c axis by classical N—H⋯O(diazo­carbon­yl)...

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Detalles Bibliográficos
Autores principales: Mehmood, Tahir, Zaidi, Javid H., Jones, Peter G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970119/
https://www.ncbi.nlm.nih.gov/pubmed/21577535
http://dx.doi.org/10.1107/S1600536809030815
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author Mehmood, Tahir
Zaidi, Javid H.
Jones, Peter G.
author_facet Mehmood, Tahir
Zaidi, Javid H.
Jones, Peter G.
author_sort Mehmood, Tahir
collection PubMed
description In the enanti­omerically pure title compound, C(11)H(19)N(3)O(3)S, the chain C—N—C(O)—O—C—C (from the asymmetric carbon to a methyl of the tert-butyl group) displays an extended conformation. In the crystal, mol­ecules are linked into chains parallel to the c axis by classical N—H⋯O(diazo­carbon­yl) hydrogen bonding and an unusual inter­molecular three-centre inter­action involving the amino acid (aa) carbonyl O(aa) and the diazo­carbonyl grouping C(O)—CH—N N, with H⋯O(aa) = 2.51 Å and N⋯O(aa) = 2.8141 (14) Å.
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spelling pubmed-29701192010-12-30 tert-Butyl N-[1-diazo­acetyl-3-(methyl­sulfan­yl)prop­yl]carbamate Mehmood, Tahir Zaidi, Javid H. Jones, Peter G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the enanti­omerically pure title compound, C(11)H(19)N(3)O(3)S, the chain C—N—C(O)—O—C—C (from the asymmetric carbon to a methyl of the tert-butyl group) displays an extended conformation. In the crystal, mol­ecules are linked into chains parallel to the c axis by classical N—H⋯O(diazo­carbon­yl) hydrogen bonding and an unusual inter­molecular three-centre inter­action involving the amino acid (aa) carbonyl O(aa) and the diazo­carbonyl grouping C(O)—CH—N N, with H⋯O(aa) = 2.51 Å and N⋯O(aa) = 2.8141 (14) Å. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970119/ /pubmed/21577535 http://dx.doi.org/10.1107/S1600536809030815 Text en © Mehmood et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mehmood, Tahir
Zaidi, Javid H.
Jones, Peter G.
tert-Butyl N-[1-diazo­acetyl-3-(methyl­sulfan­yl)prop­yl]carbamate
title tert-Butyl N-[1-diazo­acetyl-3-(methyl­sulfan­yl)prop­yl]carbamate
title_full tert-Butyl N-[1-diazo­acetyl-3-(methyl­sulfan­yl)prop­yl]carbamate
title_fullStr tert-Butyl N-[1-diazo­acetyl-3-(methyl­sulfan­yl)prop­yl]carbamate
title_full_unstemmed tert-Butyl N-[1-diazo­acetyl-3-(methyl­sulfan­yl)prop­yl]carbamate
title_short tert-Butyl N-[1-diazo­acetyl-3-(methyl­sulfan­yl)prop­yl]carbamate
title_sort tert-butyl n-[1-diazo­acetyl-3-(methyl­sulfan­yl)prop­yl]carbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970119/
https://www.ncbi.nlm.nih.gov/pubmed/21577535
http://dx.doi.org/10.1107/S1600536809030815
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