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Diazido­bis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)nickel(II) monohydrate

In the crystal structure of the title compound, [Ni(N(3))(2)(C(12)H(12)N(2))(2)]·H(2)O, the Ni(II) atom is situated on a twofold axis and adopts a distorted octa­hedral geometry with the two 5,5′-dimethyl-2,2′-bipyridyl (dmbpy) and the two azide ligands in a cis arrangement. The water solvent mol­ec...

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Autores principales: Phatchimkun, Jaturong, Kongsaeree, Palangpon, Suchaichit, Nattawut, Chaichit, Narongsak
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970126/
https://www.ncbi.nlm.nih.gov/pubmed/21577389
http://dx.doi.org/10.1107/S1600536809029407
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author Phatchimkun, Jaturong
Kongsaeree, Palangpon
Suchaichit, Nattawut
Chaichit, Narongsak
author_facet Phatchimkun, Jaturong
Kongsaeree, Palangpon
Suchaichit, Nattawut
Chaichit, Narongsak
author_sort Phatchimkun, Jaturong
collection PubMed
description In the crystal structure of the title compound, [Ni(N(3))(2)(C(12)H(12)N(2))(2)]·H(2)O, the Ni(II) atom is situated on a twofold axis and adopts a distorted octa­hedral geometry with the two 5,5′-dimethyl-2,2′-bipyridyl (dmbpy) and the two azide ligands in a cis arrangement. The water solvent mol­ecule is disordered over two positions in a 1:1 ratio.
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spelling pubmed-29701262010-12-30 Diazido­bis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)nickel(II) monohydrate Phatchimkun, Jaturong Kongsaeree, Palangpon Suchaichit, Nattawut Chaichit, Narongsak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ni(N(3))(2)(C(12)H(12)N(2))(2)]·H(2)O, the Ni(II) atom is situated on a twofold axis and adopts a distorted octa­hedral geometry with the two 5,5′-dimethyl-2,2′-bipyridyl (dmbpy) and the two azide ligands in a cis arrangement. The water solvent mol­ecule is disordered over two positions in a 1:1 ratio. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970126/ /pubmed/21577389 http://dx.doi.org/10.1107/S1600536809029407 Text en © Phatchimkun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Phatchimkun, Jaturong
Kongsaeree, Palangpon
Suchaichit, Nattawut
Chaichit, Narongsak
Diazido­bis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)nickel(II) monohydrate
title Diazido­bis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)nickel(II) monohydrate
title_full Diazido­bis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)nickel(II) monohydrate
title_fullStr Diazido­bis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)nickel(II) monohydrate
title_full_unstemmed Diazido­bis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)nickel(II) monohydrate
title_short Diazido­bis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)nickel(II) monohydrate
title_sort diazido­bis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) n,n′)nickel(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970126/
https://www.ncbi.nlm.nih.gov/pubmed/21577389
http://dx.doi.org/10.1107/S1600536809029407
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