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Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)nickel(II) monohydrate
In the crystal structure of the title compound, [Ni(N(3))(2)(C(12)H(12)N(2))(2)]·H(2)O, the Ni(II) atom is situated on a twofold axis and adopts a distorted octahedral geometry with the two 5,5′-dimethyl-2,2′-bipyridyl (dmbpy) and the two azide ligands in a cis arrangement. The water solvent molec...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970126/ https://www.ncbi.nlm.nih.gov/pubmed/21577389 http://dx.doi.org/10.1107/S1600536809029407 |
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author | Phatchimkun, Jaturong Kongsaeree, Palangpon Suchaichit, Nattawut Chaichit, Narongsak |
author_facet | Phatchimkun, Jaturong Kongsaeree, Palangpon Suchaichit, Nattawut Chaichit, Narongsak |
author_sort | Phatchimkun, Jaturong |
collection | PubMed |
description | In the crystal structure of the title compound, [Ni(N(3))(2)(C(12)H(12)N(2))(2)]·H(2)O, the Ni(II) atom is situated on a twofold axis and adopts a distorted octahedral geometry with the two 5,5′-dimethyl-2,2′-bipyridyl (dmbpy) and the two azide ligands in a cis arrangement. The water solvent molecule is disordered over two positions in a 1:1 ratio. |
format | Text |
id | pubmed-2970126 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29701262010-12-30 Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)nickel(II) monohydrate Phatchimkun, Jaturong Kongsaeree, Palangpon Suchaichit, Nattawut Chaichit, Narongsak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ni(N(3))(2)(C(12)H(12)N(2))(2)]·H(2)O, the Ni(II) atom is situated on a twofold axis and adopts a distorted octahedral geometry with the two 5,5′-dimethyl-2,2′-bipyridyl (dmbpy) and the two azide ligands in a cis arrangement. The water solvent molecule is disordered over two positions in a 1:1 ratio. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970126/ /pubmed/21577389 http://dx.doi.org/10.1107/S1600536809029407 Text en © Phatchimkun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Phatchimkun, Jaturong Kongsaeree, Palangpon Suchaichit, Nattawut Chaichit, Narongsak Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)nickel(II) monohydrate |
title | Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ(2)
N,N′)nickel(II) monohydrate |
title_full | Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ(2)
N,N′)nickel(II) monohydrate |
title_fullStr | Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ(2)
N,N′)nickel(II) monohydrate |
title_full_unstemmed | Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ(2)
N,N′)nickel(II) monohydrate |
title_short | Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ(2)
N,N′)nickel(II) monohydrate |
title_sort | diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ(2)
n,n′)nickel(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970126/ https://www.ncbi.nlm.nih.gov/pubmed/21577389 http://dx.doi.org/10.1107/S1600536809029407 |
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