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Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide]silver(I) trifluoro­acetate

In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)CO(2), the Ag(I) ion is coordinated by two N atoms of the pyridine rings of two N′-(3-cyano­benzyl­idene)isonicotinohydrazide ligands in a nearly linear geometry. In the crystal structure, a combination of close contacts formed via Ag⋯N inter­actio...

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Autores principales: Niu, Cao-Yuan, Zhang, Hai-Yan, Dang, Yu-Li, Kou, Chun-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970130/
https://www.ncbi.nlm.nih.gov/pubmed/21577396
http://dx.doi.org/10.1107/S1600536809029183
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author Niu, Cao-Yuan
Zhang, Hai-Yan
Dang, Yu-Li
Kou, Chun-Hong
author_facet Niu, Cao-Yuan
Zhang, Hai-Yan
Dang, Yu-Li
Kou, Chun-Hong
author_sort Niu, Cao-Yuan
collection PubMed
description In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)CO(2), the Ag(I) ion is coordinated by two N atoms of the pyridine rings of two N′-(3-cyano­benzyl­idene)isonicotinohydrazide ligands in a nearly linear geometry. In the crystal structure, a combination of close contacts formed via Ag⋯N inter­actions [Ag⋯N = 3.098 (2) and 3.261 (2) Å] from symmetry-related mol­ecules and inter­molecular N—H⋯O hydrogen bonds between CF(3)CO(2) (−) anions and the hydrazone groups of two ligands give rise to chains. Furthermore, there are Ag⋯O inter­actions with a separation of 2.765 (2) Å between chains. The F atoms of the CF(3)CO(2) (−) anion are disordered over two sites with refined occupancies of 0.593 (5) and 0.407 (5).
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spelling pubmed-29701302010-12-30 Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide]silver(I) trifluoro­acetate Niu, Cao-Yuan Zhang, Hai-Yan Dang, Yu-Li Kou, Chun-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)CO(2), the Ag(I) ion is coordinated by two N atoms of the pyridine rings of two N′-(3-cyano­benzyl­idene)isonicotinohydrazide ligands in a nearly linear geometry. In the crystal structure, a combination of close contacts formed via Ag⋯N inter­actions [Ag⋯N = 3.098 (2) and 3.261 (2) Å] from symmetry-related mol­ecules and inter­molecular N—H⋯O hydrogen bonds between CF(3)CO(2) (−) anions and the hydrazone groups of two ligands give rise to chains. Furthermore, there are Ag⋯O inter­actions with a separation of 2.765 (2) Å between chains. The F atoms of the CF(3)CO(2) (−) anion are disordered over two sites with refined occupancies of 0.593 (5) and 0.407 (5). International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970130/ /pubmed/21577396 http://dx.doi.org/10.1107/S1600536809029183 Text en © Niu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Niu, Cao-Yuan
Zhang, Hai-Yan
Dang, Yu-Li
Kou, Chun-Hong
Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide]silver(I) trifluoro­acetate
title Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide]silver(I) trifluoro­acetate
title_full Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide]silver(I) trifluoro­acetate
title_fullStr Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide]silver(I) trifluoro­acetate
title_full_unstemmed Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide]silver(I) trifluoro­acetate
title_short Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide]silver(I) trifluoro­acetate
title_sort bis[n′-(3-cyano­benzyl­idene)isonicotino­hydrazide]silver(i) trifluoro­acetate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970130/
https://www.ncbi.nlm.nih.gov/pubmed/21577396
http://dx.doi.org/10.1107/S1600536809029183
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