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Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide]silver(I) trifluoroacetate
In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)CO(2), the Ag(I) ion is coordinated by two N atoms of the pyridine rings of two N′-(3-cyanobenzylidene)isonicotinohydrazide ligands in a nearly linear geometry. In the crystal structure, a combination of close contacts formed via Ag⋯N interactio...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970130/ https://www.ncbi.nlm.nih.gov/pubmed/21577396 http://dx.doi.org/10.1107/S1600536809029183 |
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author | Niu, Cao-Yuan Zhang, Hai-Yan Dang, Yu-Li Kou, Chun-Hong |
author_facet | Niu, Cao-Yuan Zhang, Hai-Yan Dang, Yu-Li Kou, Chun-Hong |
author_sort | Niu, Cao-Yuan |
collection | PubMed |
description | In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)CO(2), the Ag(I) ion is coordinated by two N atoms of the pyridine rings of two N′-(3-cyanobenzylidene)isonicotinohydrazide ligands in a nearly linear geometry. In the crystal structure, a combination of close contacts formed via Ag⋯N interactions [Ag⋯N = 3.098 (2) and 3.261 (2) Å] from symmetry-related molecules and intermolecular N—H⋯O hydrogen bonds between CF(3)CO(2) (−) anions and the hydrazone groups of two ligands give rise to chains. Furthermore, there are Ag⋯O interactions with a separation of 2.765 (2) Å between chains. The F atoms of the CF(3)CO(2) (−) anion are disordered over two sites with refined occupancies of 0.593 (5) and 0.407 (5). |
format | Text |
id | pubmed-2970130 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29701302010-12-30 Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide]silver(I) trifluoroacetate Niu, Cao-Yuan Zhang, Hai-Yan Dang, Yu-Li Kou, Chun-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)CO(2), the Ag(I) ion is coordinated by two N atoms of the pyridine rings of two N′-(3-cyanobenzylidene)isonicotinohydrazide ligands in a nearly linear geometry. In the crystal structure, a combination of close contacts formed via Ag⋯N interactions [Ag⋯N = 3.098 (2) and 3.261 (2) Å] from symmetry-related molecules and intermolecular N—H⋯O hydrogen bonds between CF(3)CO(2) (−) anions and the hydrazone groups of two ligands give rise to chains. Furthermore, there are Ag⋯O interactions with a separation of 2.765 (2) Å between chains. The F atoms of the CF(3)CO(2) (−) anion are disordered over two sites with refined occupancies of 0.593 (5) and 0.407 (5). International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970130/ /pubmed/21577396 http://dx.doi.org/10.1107/S1600536809029183 Text en © Niu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Niu, Cao-Yuan Zhang, Hai-Yan Dang, Yu-Li Kou, Chun-Hong Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide]silver(I) trifluoroacetate |
title | Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide]silver(I) trifluoroacetate |
title_full | Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide]silver(I) trifluoroacetate |
title_fullStr | Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide]silver(I) trifluoroacetate |
title_full_unstemmed | Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide]silver(I) trifluoroacetate |
title_short | Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide]silver(I) trifluoroacetate |
title_sort | bis[n′-(3-cyanobenzylidene)isonicotinohydrazide]silver(i) trifluoroacetate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970130/ https://www.ncbi.nlm.nih.gov/pubmed/21577396 http://dx.doi.org/10.1107/S1600536809029183 |
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