(Z)-6-[(5-Chloro-2-hydroxy­phenyl)­aminomethyl­ene]-2-ethoxy­cyclo­hexa-2,4-dienone

The title compound, C(15)H(14)ClNO(3), exists as the keto–amine form in the crystal and two intra­molecular N—H⋯O hydrogen bonds are observed. The aromatic rings are oriented at a dihedral angle of 5.85 (8)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecule...

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Detalles Bibliográficos
Autores principales: Özek, Arzu, Albayrak, Çiğdem, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970131/
https://www.ncbi.nlm.nih.gov/pubmed/21577562
http://dx.doi.org/10.1107/S1600536809031298
Descripción
Sumario:The title compound, C(15)H(14)ClNO(3), exists as the keto–amine form in the crystal and two intra­molecular N—H⋯O hydrogen bonds are observed. The aromatic rings are oriented at a dihedral angle of 5.85 (8)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into chains. A π–π contact between the benzene rings [centroid–centroid distance = 3.6623 (10) Å] further stabilizes the structure.

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