(Z)-6-[(5-Chloro-2-hydroxy­phenyl)­aminomethyl­ene]-2-ethoxy­cyclo­hexa-2,4-dienone

The title compound, C(15)H(14)ClNO(3), exists as the keto–amine form in the crystal and two intra­molecular N—H⋯O hydrogen bonds are observed. The aromatic rings are oriented at a dihedral angle of 5.85 (8)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecule...

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Detalles Bibliográficos
Autores principales: Özek, Arzu, Albayrak, Çiğdem, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970131/
https://www.ncbi.nlm.nih.gov/pubmed/21577562
http://dx.doi.org/10.1107/S1600536809031298
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author Özek, Arzu
Albayrak, Çiğdem
Büyükgüngör, Orhan
author_facet Özek, Arzu
Albayrak, Çiğdem
Büyükgüngör, Orhan
author_sort Özek, Arzu
collection PubMed
description The title compound, C(15)H(14)ClNO(3), exists as the keto–amine form in the crystal and two intra­molecular N—H⋯O hydrogen bonds are observed. The aromatic rings are oriented at a dihedral angle of 5.85 (8)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into chains. A π–π contact between the benzene rings [centroid–centroid distance = 3.6623 (10) Å] further stabilizes the structure.
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spelling pubmed-29701312010-12-30 (Z)-6-[(5-Chloro-2-hydroxy­phenyl)­aminomethyl­ene]-2-ethoxy­cyclo­hexa-2,4-dienone Özek, Arzu Albayrak, Çiğdem Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(14)ClNO(3), exists as the keto–amine form in the crystal and two intra­molecular N—H⋯O hydrogen bonds are observed. The aromatic rings are oriented at a dihedral angle of 5.85 (8)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into chains. A π–π contact between the benzene rings [centroid–centroid distance = 3.6623 (10) Å] further stabilizes the structure. International Union of Crystallography 2009-08-15 /pmc/articles/PMC2970131/ /pubmed/21577562 http://dx.doi.org/10.1107/S1600536809031298 Text en © Özek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Özek, Arzu
Albayrak, Çiğdem
Büyükgüngör, Orhan
(Z)-6-[(5-Chloro-2-hydroxy­phenyl)­aminomethyl­ene]-2-ethoxy­cyclo­hexa-2,4-dienone
title (Z)-6-[(5-Chloro-2-hydroxy­phenyl)­aminomethyl­ene]-2-ethoxy­cyclo­hexa-2,4-dienone
title_full (Z)-6-[(5-Chloro-2-hydroxy­phenyl)­aminomethyl­ene]-2-ethoxy­cyclo­hexa-2,4-dienone
title_fullStr (Z)-6-[(5-Chloro-2-hydroxy­phenyl)­aminomethyl­ene]-2-ethoxy­cyclo­hexa-2,4-dienone
title_full_unstemmed (Z)-6-[(5-Chloro-2-hydroxy­phenyl)­aminomethyl­ene]-2-ethoxy­cyclo­hexa-2,4-dienone
title_short (Z)-6-[(5-Chloro-2-hydroxy­phenyl)­aminomethyl­ene]-2-ethoxy­cyclo­hexa-2,4-dienone
title_sort (z)-6-[(5-chloro-2-hydroxy­phenyl)­aminomethyl­ene]-2-ethoxy­cyclo­hexa-2,4-dienone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970131/
https://www.ncbi.nlm.nih.gov/pubmed/21577562
http://dx.doi.org/10.1107/S1600536809031298
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