Di-μ-oxido-bis­[(4-formyl-2-methoxy­phenolato-κO (1))oxido(1,10-phenan­throline-κ(2) N,N′)vanadium(V)]

The title complex, [V(2)(C(8)H(7)O(3))(2)O(4)(C(12)H(8)N(2))(2)], is a centrosymmetric dimer formed by two V(V) complex units bridged by two μ(2)-oxido groups. The V(V) atom is six-coordinated by three oxide O atoms, one O atom from a vanillinate ligand and two N atoms from a 1,10-phenanthroline lig...

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Detalles Bibliográficos
Autores principales: Guo, Zhenghua, Li, Lianzhi, Xu, Tao, Li, Jinghong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970134/
https://www.ncbi.nlm.nih.gov/pubmed/21577458
http://dx.doi.org/10.1107/S1600536809032516
Descripción
Sumario:The title complex, [V(2)(C(8)H(7)O(3))(2)O(4)(C(12)H(8)N(2))(2)], is a centrosymmetric dimer formed by two V(V) complex units bridged by two μ(2)-oxido groups. The V(V) atom is six-coordinated by three oxide O atoms, one O atom from a vanillinate ligand and two N atoms from a 1,10-phenanthroline ligand in a significantly distorted octa­hedral geometry. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds connect the mol­ecules into a three-dimensional network.

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