Di-μ-oxido-bis­[(4-formyl-2-methoxy­phenolato-κO (1))oxido(1,10-phenan­throline-κ(2) N,N′)vanadium(V)]

The title complex, [V(2)(C(8)H(7)O(3))(2)O(4)(C(12)H(8)N(2))(2)], is a centrosymmetric dimer formed by two V(V) complex units bridged by two μ(2)-oxido groups. The V(V) atom is six-coordinated by three oxide O atoms, one O atom from a vanillinate ligand and two N atoms from a 1,10-phenanthroline lig...

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Detalles Bibliográficos
Autores principales: Guo, Zhenghua, Li, Lianzhi, Xu, Tao, Li, Jinghong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970134/
https://www.ncbi.nlm.nih.gov/pubmed/21577458
http://dx.doi.org/10.1107/S1600536809032516
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author Guo, Zhenghua
Li, Lianzhi
Xu, Tao
Li, Jinghong
author_facet Guo, Zhenghua
Li, Lianzhi
Xu, Tao
Li, Jinghong
author_sort Guo, Zhenghua
collection PubMed
description The title complex, [V(2)(C(8)H(7)O(3))(2)O(4)(C(12)H(8)N(2))(2)], is a centrosymmetric dimer formed by two V(V) complex units bridged by two μ(2)-oxido groups. The V(V) atom is six-coordinated by three oxide O atoms, one O atom from a vanillinate ligand and two N atoms from a 1,10-phenanthroline ligand in a significantly distorted octa­hedral geometry. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds connect the mol­ecules into a three-dimensional network.
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spelling pubmed-29701342010-12-30 Di-μ-oxido-bis­[(4-formyl-2-methoxy­phenolato-κO (1))oxido(1,10-phenan­throline-κ(2) N,N′)vanadium(V)] Guo, Zhenghua Li, Lianzhi Xu, Tao Li, Jinghong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [V(2)(C(8)H(7)O(3))(2)O(4)(C(12)H(8)N(2))(2)], is a centrosymmetric dimer formed by two V(V) complex units bridged by two μ(2)-oxido groups. The V(V) atom is six-coordinated by three oxide O atoms, one O atom from a vanillinate ligand and two N atoms from a 1,10-phenanthroline ligand in a significantly distorted octa­hedral geometry. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds connect the mol­ecules into a three-dimensional network. International Union of Crystallography 2009-08-22 /pmc/articles/PMC2970134/ /pubmed/21577458 http://dx.doi.org/10.1107/S1600536809032516 Text en © Guo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Zhenghua
Li, Lianzhi
Xu, Tao
Li, Jinghong
Di-μ-oxido-bis­[(4-formyl-2-methoxy­phenolato-κO (1))oxido(1,10-phenan­throline-κ(2) N,N′)vanadium(V)]
title Di-μ-oxido-bis­[(4-formyl-2-methoxy­phenolato-κO (1))oxido(1,10-phenan­throline-κ(2) N,N′)vanadium(V)]
title_full Di-μ-oxido-bis­[(4-formyl-2-methoxy­phenolato-κO (1))oxido(1,10-phenan­throline-κ(2) N,N′)vanadium(V)]
title_fullStr Di-μ-oxido-bis­[(4-formyl-2-methoxy­phenolato-κO (1))oxido(1,10-phenan­throline-κ(2) N,N′)vanadium(V)]
title_full_unstemmed Di-μ-oxido-bis­[(4-formyl-2-methoxy­phenolato-κO (1))oxido(1,10-phenan­throline-κ(2) N,N′)vanadium(V)]
title_short Di-μ-oxido-bis­[(4-formyl-2-methoxy­phenolato-κO (1))oxido(1,10-phenan­throline-κ(2) N,N′)vanadium(V)]
title_sort di-μ-oxido-bis­[(4-formyl-2-methoxy­phenolato-κo (1))oxido(1,10-phenan­throline-κ(2) n,n′)vanadium(v)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970134/
https://www.ncbi.nlm.nih.gov/pubmed/21577458
http://dx.doi.org/10.1107/S1600536809032516
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AT lijinghong dimoxidobis4formyl2methoxyphenolatoko1oxido110phenanthrolinek2nnvanadiumv

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