trans-Di-μ-iodido-bis­[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]

The complete molecule of the dinuclear title compound, [Hg(2)I(4)(C(7)H(4)S(3))(2)], is generated by crystallographic inversion symmetry. The complex has a dimeric structure in which each Hg(II) ion adopts a tetra­hedral geometry and is coordinated by two bridging I atoms, one terminal iodide ion an...

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Detalles Bibliográficos
Autores principales: Laifa, El Adoui, Bendjeddou, Lamia, Boudraa, Naouel, Dahaoui, Slimane, Lecomte, Claude
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970135/
https://www.ncbi.nlm.nih.gov/pubmed/21577433
http://dx.doi.org/10.1107/S1600536809032152
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author Laifa, El Adoui
Bendjeddou, Lamia
Boudraa, Naouel
Dahaoui, Slimane
Lecomte, Claude
author_facet Laifa, El Adoui
Bendjeddou, Lamia
Boudraa, Naouel
Dahaoui, Slimane
Lecomte, Claude
author_sort Laifa, El Adoui
collection PubMed
description The complete molecule of the dinuclear title compound, [Hg(2)I(4)(C(7)H(4)S(3))(2)], is generated by crystallographic inversion symmetry. The complex has a dimeric structure in which each Hg(II) ion adopts a tetra­hedral geometry and is coordinated by two bridging I atoms, one terminal iodide ion and one thio­carbonyl S atom (C=S) of the ligand. The square plane formed by the Hg and I atoms and their symmetry counterparts makes a dihedral angle of 89.66 (3)° with the DDT plane. There is no classical hydrogen bonding, but weak S⋯S inter­actions of 3.4452 (7) and 3.6859 (7) Å maintain the cohesion of the crystal structure.
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spelling pubmed-29701352010-12-30 trans-Di-μ-iodido-bis­[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)] Laifa, El Adoui Bendjeddou, Lamia Boudraa, Naouel Dahaoui, Slimane Lecomte, Claude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete molecule of the dinuclear title compound, [Hg(2)I(4)(C(7)H(4)S(3))(2)], is generated by crystallographic inversion symmetry. The complex has a dimeric structure in which each Hg(II) ion adopts a tetra­hedral geometry and is coordinated by two bridging I atoms, one terminal iodide ion and one thio­carbonyl S atom (C=S) of the ligand. The square plane formed by the Hg and I atoms and their symmetry counterparts makes a dihedral angle of 89.66 (3)° with the DDT plane. There is no classical hydrogen bonding, but weak S⋯S inter­actions of 3.4452 (7) and 3.6859 (7) Å maintain the cohesion of the crystal structure. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2970135/ /pubmed/21577433 http://dx.doi.org/10.1107/S1600536809032152 Text en © Laifa et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Laifa, El Adoui
Bendjeddou, Lamia
Boudraa, Naouel
Dahaoui, Slimane
Lecomte, Claude
trans-Di-μ-iodido-bis­[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
title trans-Di-μ-iodido-bis­[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
title_full trans-Di-μ-iodido-bis­[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
title_fullStr trans-Di-μ-iodido-bis­[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
title_full_unstemmed trans-Di-μ-iodido-bis­[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
title_short trans-Di-μ-iodido-bis­[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
title_sort trans-di-μ-iodido-bis­[(3h-1,2-benzodithiole-3-thione)iodidomercury(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970135/
https://www.ncbi.nlm.nih.gov/pubmed/21577433
http://dx.doi.org/10.1107/S1600536809032152
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