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Poly[bis(dimethylammonium) [bis(dimethylamine-κN)tris(μ(2)-terephthalato-κ(2) O (1):O (4))dizinc(II)] N,N-dimethylformamide disolvate hexahydrate]
The title compound, {(C(2)H(8)N)(2)[Zn(2)(C(8)H(4)O(4))(3)(C(2)H(7)N)(2)]·2C(3)H(7)NO·6H(2)O}(n), consists of two-dimensional non-interpenetrated sheets with 6(3) topology, which are stacked together in an …ABAB… packing mode along the c axis. The distance between adjacent A and B sheets is ca 7.3 ...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970138/ https://www.ncbi.nlm.nih.gov/pubmed/21577426 http://dx.doi.org/10.1107/S1600536809030177 |
Sumario: | The title compound, {(C(2)H(8)N)(2)[Zn(2)(C(8)H(4)O(4))(3)(C(2)H(7)N)(2)]·2C(3)H(7)NO·6H(2)O}(n), consists of two-dimensional non-interpenetrated sheets with 6(3) topology, which are stacked together in an …ABAB… packing mode along the c axis. The distance between adjacent A and B sheets is ca 7.3 Å. In the structure, the Zn(II) center is coordinated by three O atoms from three terephthalate groups and one N atom from one dimethylamine ligand, adopting a distorted tetrahedral geometry. All solvent water molecules are disordered. In the structure, N—H⋯O and O—H⋯O hydrogen bonds are observed. |
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