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Poly[bis(dimethylammonium) [bis(dimethylamine-κN)tris(μ(2)-terephthalato-κ(2) O (1):O (4))dizinc(II)] N,N-dimethylformamide disolvate hexahydrate]
The title compound, {(C(2)H(8)N)(2)[Zn(2)(C(8)H(4)O(4))(3)(C(2)H(7)N)(2)]·2C(3)H(7)NO·6H(2)O}(n), consists of two-dimensional non-interpenetrated sheets with 6(3) topology, which are stacked together in an …ABAB… packing mode along the c axis. The distance between adjacent A and B sheets is ca 7.3 ...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970138/ https://www.ncbi.nlm.nih.gov/pubmed/21577426 http://dx.doi.org/10.1107/S1600536809030177 |
| _version_ | 1782190357829648384 |
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| author | Xiao, Jie Zhou, Hu Yuan, Ai-Hua |
| author_facet | Xiao, Jie Zhou, Hu Yuan, Ai-Hua |
| author_sort | Xiao, Jie |
| collection | PubMed |
| description | The title compound, {(C(2)H(8)N)(2)[Zn(2)(C(8)H(4)O(4))(3)(C(2)H(7)N)(2)]·2C(3)H(7)NO·6H(2)O}(n), consists of two-dimensional non-interpenetrated sheets with 6(3) topology, which are stacked together in an …ABAB… packing mode along the c axis. The distance between adjacent A and B sheets is ca 7.3 Å. In the structure, the Zn(II) center is coordinated by three O atoms from three terephthalate groups and one N atom from one dimethylamine ligand, adopting a distorted tetrahedral geometry. All solvent water molecules are disordered. In the structure, N—H⋯O and O—H⋯O hydrogen bonds are observed. |
| format | Text |
| id | pubmed-2970138 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29701382010-12-30 Poly[bis(dimethylammonium) [bis(dimethylamine-κN)tris(μ(2)-terephthalato-κ(2) O (1):O (4))dizinc(II)] N,N-dimethylformamide disolvate hexahydrate] Xiao, Jie Zhou, Hu Yuan, Ai-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {(C(2)H(8)N)(2)[Zn(2)(C(8)H(4)O(4))(3)(C(2)H(7)N)(2)]·2C(3)H(7)NO·6H(2)O}(n), consists of two-dimensional non-interpenetrated sheets with 6(3) topology, which are stacked together in an …ABAB… packing mode along the c axis. The distance between adjacent A and B sheets is ca 7.3 Å. In the structure, the Zn(II) center is coordinated by three O atoms from three terephthalate groups and one N atom from one dimethylamine ligand, adopting a distorted tetrahedral geometry. All solvent water molecules are disordered. In the structure, N—H⋯O and O—H⋯O hydrogen bonds are observed. International Union of Crystallography 2009-08-15 /pmc/articles/PMC2970138/ /pubmed/21577426 http://dx.doi.org/10.1107/S1600536809030177 Text en © Xiao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xiao, Jie Zhou, Hu Yuan, Ai-Hua Poly[bis(dimethylammonium) [bis(dimethylamine-κN)tris(μ(2)-terephthalato-κ(2) O (1):O (4))dizinc(II)] N,N-dimethylformamide disolvate hexahydrate] |
| title | Poly[bis(dimethylammonium) [bis(dimethylamine-κN)tris(μ(2)-terephthalato-κ(2)
O
(1):O
(4))dizinc(II)] N,N-dimethylformamide disolvate hexahydrate] |
| title_full | Poly[bis(dimethylammonium) [bis(dimethylamine-κN)tris(μ(2)-terephthalato-κ(2)
O
(1):O
(4))dizinc(II)] N,N-dimethylformamide disolvate hexahydrate] |
| title_fullStr | Poly[bis(dimethylammonium) [bis(dimethylamine-κN)tris(μ(2)-terephthalato-κ(2)
O
(1):O
(4))dizinc(II)] N,N-dimethylformamide disolvate hexahydrate] |
| title_full_unstemmed | Poly[bis(dimethylammonium) [bis(dimethylamine-κN)tris(μ(2)-terephthalato-κ(2)
O
(1):O
(4))dizinc(II)] N,N-dimethylformamide disolvate hexahydrate] |
| title_short | Poly[bis(dimethylammonium) [bis(dimethylamine-κN)tris(μ(2)-terephthalato-κ(2)
O
(1):O
(4))dizinc(II)] N,N-dimethylformamide disolvate hexahydrate] |
| title_sort | poly[bis(dimethylammonium) [bis(dimethylamine-κn)tris(μ(2)-terephthalato-κ(2)
o
(1):o
(4))dizinc(ii)] n,n-dimethylformamide disolvate hexahydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970138/ https://www.ncbi.nlm.nih.gov/pubmed/21577426 http://dx.doi.org/10.1107/S1600536809030177 |
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